Nouvelles méthodes de génération de radicaux silylés : application à des processus radicalaires sans étain

Nouvelles méthodes de génération de radicaux silylés : application à des processus radicalaires sans étain

Deux nouveaux concepts, visant à reproduire la chimie radicalaire des diétains à l’aide de radicaux centrés sur le silicium, sont présentés à travers ce manuscrit. Le premier concept introduit les “silaboranes”, des molécules constituées d’un motif de type silane et d’un atome de bore. Ceux-ci ont...

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Bibliographic Details
Main Author:	Rouquet, Guy
Other Authors:	Bordeaux 1
Language:	fr
Published:	2010
Subjects:	Chimie radicalaire sans étain Diétains Sulfones Silaboranes Tris(triméthylsilyle) Bore Silicium Radicaux silylés SHi (Substitution homolitique intramoléculaire) Transfert d’hydrogène intramoléculaire Beta-fragmentation Allyl tris(triméthysilyl)silane Radicaux sulfonylés Tin-free radical chemistry Ditin Tris(trimethylsilyl) Boron Silicon Silyl radicals SHi (Intramolecular Homolytic Substitution) Intramolecular hydrogen transfer Allyl tris(trimethysilyl)silane Sulfonyl radicals
Online Access:	http://www.theses.fr/2010BOR14180/document

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