Immobilized metallodithiolate ligand supports for construction of bioinorganic model complexes
The A-cluster active site in acetyl coA synthase exploits a Ni(CGC)2- metallopeptide as a bidentate ligand to chelate the catalytically active square-planar nickel center used to produce acetyl coA. As Nature utilizes polypeptides to isolate and stabilize the active sites, we have set out to immobil...
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| Format: | Others |
| Language: | en_US |
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2010
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| Online Access: | http://hdl.handle.net/1969.1/ETD-TAMU-2445 http://hdl.handle.net/1969.1/ETD-TAMU-2445 |