Synthesis and Electric Field-Manipulation of High Aspect Ratio Barium Titanate

The objective of this thesis is to develop high dielectric constant nanoparticle dispersion for switchable aircraft antenna systems. Two steps were designed to achieve the objective. First, obtain high dielectric, high aspect ratio nanoparticles and disperse them in dielectric oil medium. Second, ma...

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Main Author: Li, Junjia
Other Authors: Ounaies, Zoubeida
Format: Others
Language:en_US
Published: 2012
Subjects:
Online Access:http://hdl.handle.net/1969.1/ETD-TAMU-2011-05-9418
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spelling ndltd-tamu.edu-oai-repository.tamu.edu-1969.1-ETD-TAMU-2011-05-94182013-01-08T10:43:58ZSynthesis and Electric Field-Manipulation of High Aspect Ratio Barium TitanateLi, JunjiaAlignmentSynthesisElectric field manipulationHigh aspect ratioBarium titanateDielectric constantThe objective of this thesis is to develop high dielectric constant nanoparticle dispersion for switchable aircraft antenna systems. Two steps were designed to achieve the objective. First, obtain high dielectric, high aspect ratio nanoparticles and disperse them in dielectric oil medium. Second, manipulate the particle-oil dispersion using an external alternating current (AC) electric field to increase the effective dielectric constant. In order to obtain high dielectric dispersions, different sizes and shapes of titanium dioxide (TiO2) and barium titanate (BaTiO3) nanoparticles were purchased and measured. However, after a number of experiments detailed in the thesis, it was found that none of the commercially available nanoparticles could satisfy our requirements for a minimum effective dielectric constant. Thus, to achieve the goals above, we synthesized high aspect ratio BaTiO3 nanowires with BaC2O4 and TiO2 powders as precursors using a molten salt method. The as-synthesized BaTiO3 nanowires were characterized using scanning electron microscopy (SEM), X-ray diffraction (XRD), and energy dispersive spectroscopy (EDS) mapping. The nanowires have a diameter ranging from 100 nm to 300 nm, and their lengths range from 1.5 micrometers to 5 micrometers. Mechanical stirring and bath sonication were used to obtain even colloidal dispersions. Different concentrations of BaTiO3 nanoparticles well dispersed in the oil medium were successfully manipulated using AC electric field. To monitor the change in microstructure of BaTiO3 nanoparticles, optical microscopy was used to observe the alignment of particles in the sample under the applied electric field. Various parameters including the magnitude, frequency, and duration of the electric field, and the concentration of BaTiO3 nanoparticles were investigated to achieve the optimal alignment of nanoparticles. The experimental results were validated by theoretical analysis using Maxwell-Garnett mixing rule. It was demonstrated that the effective dielectric constant of the colloidal dispersions would increase with the increase of the magnitude, frequency and duration of applied electric field. Synthesized BaTiO3 nanowire-based dispersions exhibit significant enhancement of the effective dielectric constant compared to other colloidal materials. The effective dielectric constant of 5 wt percent BaTiO3-oil dispersions could reach up to 10 when aligned at 1000 V/mm electric field at 1 kHz frequency for 1 hour.Ounaies, ZoubeidaLagoudas, Dimitris2012-07-16T15:57:15Z2012-07-16T20:28:19Z2012-07-16T15:57:15Z2012-07-16T20:28:19Z2011-052012-07-16May 2011thesistextapplication/pdfhttp://hdl.handle.net/1969.1/ETD-TAMU-2011-05-9418en_US
collection NDLTD
language en_US
format Others
sources NDLTD
topic Alignment
Synthesis
Electric field manipulation
High aspect ratio
Barium titanate
Dielectric constant
spellingShingle Alignment
Synthesis
Electric field manipulation
High aspect ratio
Barium titanate
Dielectric constant
Li, Junjia
Synthesis and Electric Field-Manipulation of High Aspect Ratio Barium Titanate
description The objective of this thesis is to develop high dielectric constant nanoparticle dispersion for switchable aircraft antenna systems. Two steps were designed to achieve the objective. First, obtain high dielectric, high aspect ratio nanoparticles and disperse them in dielectric oil medium. Second, manipulate the particle-oil dispersion using an external alternating current (AC) electric field to increase the effective dielectric constant. In order to obtain high dielectric dispersions, different sizes and shapes of titanium dioxide (TiO2) and barium titanate (BaTiO3) nanoparticles were purchased and measured. However, after a number of experiments detailed in the thesis, it was found that none of the commercially available nanoparticles could satisfy our requirements for a minimum effective dielectric constant. Thus, to achieve the goals above, we synthesized high aspect ratio BaTiO3 nanowires with BaC2O4 and TiO2 powders as precursors using a molten salt method. The as-synthesized BaTiO3 nanowires were characterized using scanning electron microscopy (SEM), X-ray diffraction (XRD), and energy dispersive spectroscopy (EDS) mapping. The nanowires have a diameter ranging from 100 nm to 300 nm, and their lengths range from 1.5 micrometers to 5 micrometers. Mechanical stirring and bath sonication were used to obtain even colloidal dispersions. Different concentrations of BaTiO3 nanoparticles well dispersed in the oil medium were successfully manipulated using AC electric field. To monitor the change in microstructure of BaTiO3 nanoparticles, optical microscopy was used to observe the alignment of particles in the sample under the applied electric field. Various parameters including the magnitude, frequency, and duration of the electric field, and the concentration of BaTiO3 nanoparticles were investigated to achieve the optimal alignment of nanoparticles. The experimental results were validated by theoretical analysis using Maxwell-Garnett mixing rule. It was demonstrated that the effective dielectric constant of the colloidal dispersions would increase with the increase of the magnitude, frequency and duration of applied electric field. Synthesized BaTiO3 nanowire-based dispersions exhibit significant enhancement of the effective dielectric constant compared to other colloidal materials. The effective dielectric constant of 5 wt percent BaTiO3-oil dispersions could reach up to 10 when aligned at 1000 V/mm electric field at 1 kHz frequency for 1 hour.
author2 Ounaies, Zoubeida
author_facet Ounaies, Zoubeida
Li, Junjia
author Li, Junjia
author_sort Li, Junjia
title Synthesis and Electric Field-Manipulation of High Aspect Ratio Barium Titanate
title_short Synthesis and Electric Field-Manipulation of High Aspect Ratio Barium Titanate
title_full Synthesis and Electric Field-Manipulation of High Aspect Ratio Barium Titanate
title_fullStr Synthesis and Electric Field-Manipulation of High Aspect Ratio Barium Titanate
title_full_unstemmed Synthesis and Electric Field-Manipulation of High Aspect Ratio Barium Titanate
title_sort synthesis and electric field-manipulation of high aspect ratio barium titanate
publishDate 2012
url http://hdl.handle.net/1969.1/ETD-TAMU-2011-05-9418
work_keys_str_mv AT lijunjia synthesisandelectricfieldmanipulationofhighaspectratiobariumtitanate
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