A Short Route To Benzyl Beta-D-Glycosides Of 2-Amino-2-Deoxy-D-Glucose And -D-Allose And Elimination Of The 3-Sulfonate From Benzyl 4,6-O-Benzylidene-2-Benzyloxycarbonylamido-2-Deoxy-3-O-(Methylsulfonyl)- Beta-D-Glucopyranoside

It is one purpose of this dissertation to introduce a facile method for the preparation of β glycosides of D-glucose and D-allose. It is the second purpose of this dissertation to investigate the preparation of 2-oxazolidinones forming a bridge between C2 and C3 of allopyranose. This preparation, al...

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Bibliographic Details
Main Author: Rhoads, William Denham
Format: Others
Published: Scholarly Commons 1968
Subjects:
Online Access:https://scholarlycommons.pacific.edu/uop_etds/2832
https://scholarlycommons.pacific.edu/cgi/viewcontent.cgi?article=3831&context=uop_etds
Description
Summary:It is one purpose of this dissertation to introduce a facile method for the preparation of β glycosides of D-glucose and D-allose. It is the second purpose of this dissertation to investigate the preparation of 2-oxazolidinones forming a bridge between C2 and C3 of allopyranose. This preparation, along with the facile preparation of β-benzyl glycosides of D-glucosamine and D-allosamine, should lead to compounds which, in a few steps, can conceivably be used for coupling at positions 1 and 4.