Elektrochemický senzor s elektrodou modifikovanou derivátem ftalocyaninu pro stanovení sirných látek

The diploma thesis presents the results of the studies of thin layer film composed of N,N',N'',N'''-tetramethyl-tetra-3,4-pyridinoporphyrazinocobalt. This film is deposited on the surface of highly oriented pyrolytic graphite. The modified electrode displayed electrocat...

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Bibliographic Details
Main Author: Zlámalová, Magda
Other Authors: Nesměrák, Karel
Format: Dissertation
Language:Czech
Published: 2012
Online Access:http://www.nusl.cz/ntk/nusl-306646
Description
Summary:The diploma thesis presents the results of the studies of thin layer film composed of N,N',N'',N'''-tetramethyl-tetra-3,4-pyridinoporphyrazinocobalt. This film is deposited on the surface of highly oriented pyrolytic graphite. The modified electrode displayed electrocatalytic activity to oxidation of sulphide anions and cysteine. It has been studied the possibility of enhancement of stability of the immobilized film by the nafion. This electrode was used for the analytical determination of sulphide anions and cysteine. Keywords: highly oriented pyrolytic graphite, porphyrazines, hydrogen sulphide, cysteine, nafion, cyclic voltammetry, atomic force microscopy