Rhodium-catalyzed and uncatalyzed synthesis of boronate esters and their subsequent utility in the Suzuki realm.

This study has shown that alkythioboranes 1,3,2-dithiaborolane and 1,3,2-dithiaborinane, disproportionated significantly during their synthesis. Their interaction with 1-octene has been investigated, and the rate constants, enthalpies and entropies of the hydroboration process, have been determined....

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Main Author:	Hadebe, Siphamandla Wiseman.
Language:	en
Published:	2010
Subjects:	Heterocyclic compounds. Boranes. Olefins. Theses > Chemistry.
Online Access:	http://hdl.handle.net/10413/954

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spelling	ndltd-netd.ac.za-oai-union.ndltd.org-ukzn-oai-http---researchspace.ukzn.ac.za-10413-9542014-02-08T03:48:45ZRhodium-catalyzed and uncatalyzed synthesis of boronate esters and their subsequent utility in the Suzuki realm.Hadebe, Siphamandla Wiseman.Heterocyclic compounds.Boranes.Olefins.Theses--Chemistry.This study has shown that alkythioboranes 1,3,2-dithiaborolane and 1,3,2-dithiaborinane, disproportionated significantly during their synthesis. Their interaction with 1-octene has been investigated, and the rate constants, enthalpies and entropies of the hydroboration process, have been determined. The thermodynamic and kinetic parameters obtained have shown that the hydroboration reaction is sluggish and proceeded via an associative mechanism.Thesis (Ph.D.) - University of KwaZulu-Natal, Pietermaritzburg, 2008.2010-09-07T09:48:34Z2010-09-07T09:48:34Z2008Thesishttp://hdl.handle.net/10413/954en
collection	NDLTD
language	en
sources	NDLTD
topic	Heterocyclic compounds. Boranes. Olefins. Theses--Chemistry.
spellingShingle	Heterocyclic compounds. Boranes. Olefins. Theses--Chemistry. Hadebe, Siphamandla Wiseman. Rhodium-catalyzed and uncatalyzed synthesis of boronate esters and their subsequent utility in the Suzuki realm.
description	This study has shown that alkythioboranes 1,3,2-dithiaborolane and 1,3,2-dithiaborinane, disproportionated significantly during their synthesis. Their interaction with 1-octene has been investigated, and the rate constants, enthalpies and entropies of the hydroboration process, have been determined. The thermodynamic and kinetic parameters obtained have shown that the hydroboration reaction is sluggish and proceeded via an associative mechanism. === Thesis (Ph.D.) - University of KwaZulu-Natal, Pietermaritzburg, 2008.
author	Hadebe, Siphamandla Wiseman.
author_facet	Hadebe, Siphamandla Wiseman.
author_sort	Hadebe, Siphamandla Wiseman.
title	Rhodium-catalyzed and uncatalyzed synthesis of boronate esters and their subsequent utility in the Suzuki realm.
title_short	Rhodium-catalyzed and uncatalyzed synthesis of boronate esters and their subsequent utility in the Suzuki realm.
title_full	Rhodium-catalyzed and uncatalyzed synthesis of boronate esters and their subsequent utility in the Suzuki realm.
title_fullStr	Rhodium-catalyzed and uncatalyzed synthesis of boronate esters and their subsequent utility in the Suzuki realm.
title_full_unstemmed	Rhodium-catalyzed and uncatalyzed synthesis of boronate esters and their subsequent utility in the Suzuki realm.
title_sort	rhodium-catalyzed and uncatalyzed synthesis of boronate esters and their subsequent utility in the suzuki realm.
publishDate	2010
url	http://hdl.handle.net/10413/954
work_keys_str_mv	AT hadebesiphamandlawiseman rhodiumcatalyzedanduncatalyzedsynthesisofboronateestersandtheirsubsequentutilityinthesuzukirealm
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Rhodium-catalyzed and uncatalyzed synthesis of boronate esters and their subsequent utility in the Suzuki realm.

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