Chemie en sintese van onversadigde koolhidrate
M.Sc. (Chemistry) === A new method has been developed for the conversion of carbohydrate vicinal diols into the corresponding glycal derivatives. Treatment of suitably protected furanose 1,2-diols with mesyl chloride and triethylamine in anhydrous 1,2-dirnethoxyethane resulted in the formation of 2-...
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2015
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| Online Access: | http://hdl.handle.net/10210/14873 |
| Summary: | M.Sc. (Chemistry) === A new method has been developed for the conversion of carbohydrate vicinal diols into the corresponding glycal derivatives. Treatment of suitably protected furanose 1,2-diols with mesyl chloride and triethylamine in anhydrous 1,2-dirnethoxyethane resulted in the formation of 2-0-mesyl-furanosyl chlorides. Reductive elimination of the latter with excess active zinc dust in the presence of iodide furnished furanoid glycals ... |
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