Crystal engineering of novel organic-inorganic compounds of N- and O-donor dipyridyl ligands

Includes bibliographical references. === Crystal engineering based upon organic-inorganic compounds has made rapid progress in recent years. These compounds are known to combine the inherent advantages of both organic and inorganic substances. In this thesis, a range of metal compounds were investig...

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Main Author:	Moitsheki, Lesego J
Other Authors:	Bourne, Susan A
Format:	Doctoral Thesis
Language:	English
Published:	University of Cape Town 2014
Subjects:	Chemistry
Online Access:	http://hdl.handle.net/11427/6341

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spelling	ndltd-netd.ac.za-oai-union.ndltd.org-uct-oai-localhost-11427-63412020-07-22T05:07:56Z Crystal engineering of novel organic-inorganic compounds of N- and O-donor dipyridyl ligands Moitsheki, Lesego J Bourne, Susan A Nassimbeni, Luigi R Chemistry Includes bibliographical references. Crystal engineering based upon organic-inorganic compounds has made rapid progress in recent years. These compounds are known to combine the inherent advantages of both organic and inorganic substances. In this thesis, a range of metal compounds were investigated. These include compounds of actinides, lanthanides, transition and main group metals using dipyridyl ligands (4,4'-bipyridine-N,N'-dioxide (bpdo), 1,2-bis(4-pyridyl)ethane (BPE) and 1,2-di(4-pyridyl)ethylene (OPE) Compounds prepared were characterised by x-ray diffractometry. Thermal analysis (thermogravimetry (TG), differential scanning calorimetry (DSC) and hot stage microscopy (HSM)) was used to determine the thermal behaviour of these compounds. Microanalysis was used to confirm elemental composition. 2014-08-13T14:27:25Z 2014-08-13T14:27:25Z 2006 Doctoral Thesis Doctoral PhD http://hdl.handle.net/11427/6341 eng application/pdf University of Cape Town Faculty of Science Department of Chemistry
collection	NDLTD
language	English
format	Doctoral Thesis
sources	NDLTD
topic	Chemistry
spellingShingle	Chemistry Moitsheki, Lesego J Crystal engineering of novel organic-inorganic compounds of N- and O-donor dipyridyl ligands
description	Includes bibliographical references. === Crystal engineering based upon organic-inorganic compounds has made rapid progress in recent years. These compounds are known to combine the inherent advantages of both organic and inorganic substances. In this thesis, a range of metal compounds were investigated. These include compounds of actinides, lanthanides, transition and main group metals using dipyridyl ligands (4,4'-bipyridine-N,N'-dioxide (bpdo), 1,2-bis(4-pyridyl)ethane (BPE) and 1,2-di(4-pyridyl)ethylene (OPE) Compounds prepared were characterised by x-ray diffractometry. Thermal analysis (thermogravimetry (TG), differential scanning calorimetry (DSC) and hot stage microscopy (HSM)) was used to determine the thermal behaviour of these compounds. Microanalysis was used to confirm elemental composition.
author2	Bourne, Susan A
author_facet	Bourne, Susan A Moitsheki, Lesego J
author	Moitsheki, Lesego J
author_sort	Moitsheki, Lesego J
title	Crystal engineering of novel organic-inorganic compounds of N- and O-donor dipyridyl ligands
title_short	Crystal engineering of novel organic-inorganic compounds of N- and O-donor dipyridyl ligands
title_full	Crystal engineering of novel organic-inorganic compounds of N- and O-donor dipyridyl ligands
title_fullStr	Crystal engineering of novel organic-inorganic compounds of N- and O-donor dipyridyl ligands
title_full_unstemmed	Crystal engineering of novel organic-inorganic compounds of N- and O-donor dipyridyl ligands
title_sort	crystal engineering of novel organic-inorganic compounds of n- and o-donor dipyridyl ligands
publisher	University of Cape Town
publishDate	2014
url	http://hdl.handle.net/11427/6341
work_keys_str_mv	AT moitshekilesegoj crystalengineeringofnovelorganicinorganiccompoundsofnandodonordipyridylligands
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Crystal engineering of novel organic-inorganic compounds of N- and O-donor dipyridyl ligands

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