Aqueous phase catalysis using mono- and bimetallic transition metal complexes

Includes bibliographical references === The synthesis and characterization of monomeric and dimeric salicylaldimine water-soluble ligands is discussed. The salicylaldimine ligands (2.3-2.10) were synthesised via Schiff base condensation reactions of various amines with water-soluble sulfonated salic...

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Main Author:	Matsinha, Leah Charlie
Other Authors:	Smith, Gregory S
Format:	Doctoral Thesis
Language:	English
Published:	University of Cape Town 2016
Subjects:	Chemistry
Online Access:	http://hdl.handle.net/11427/16704

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spelling	ndltd-netd.ac.za-oai-union.ndltd.org-uct-oai-localhost-11427-167042020-07-22T05:08:04Z Aqueous phase catalysis using mono- and bimetallic transition metal complexes Matsinha, Leah Charlie Smith, Gregory S Mapolie, Selwyn F Venter, Gerhard A Chemistry Includes bibliographical references The synthesis and characterization of monomeric and dimeric salicylaldimine water-soluble ligands is discussed. The salicylaldimine ligands (2.3-2.10) were synthesised via Schiff base condensation reactions of various amines with water-soluble sulfonated salicylaldehydes (2.1 and 2.2). The ligands were characterized using various analytical and spectroscopic techniques. Complexation reactions of these water-soluble ligands (2.3-2.10) with [Rh(COD)Cl]2 gave the corresponding water-soluble mononuclear (2.11-2.14) and binuclear (2.15-2.18) Rh(I) complexes. All the complexes were characterized using nuclear magnetic resonance spectroscopy, infrared spectroscopy, single crystal X-ray diffraction (for complex 2.14), mass spectrometry, elemental analysis and melting point determinations. 2016-02-02T14:43:55Z 2016-02-02T14:43:55Z 2015 Doctoral Thesis Doctoral PhD http://hdl.handle.net/11427/16704 eng application/pdf University of Cape Town Faculty of Science Department of Chemistry
collection	NDLTD
language	English
format	Doctoral Thesis
sources	NDLTD
topic	Chemistry
spellingShingle	Chemistry Matsinha, Leah Charlie Aqueous phase catalysis using mono- and bimetallic transition metal complexes
description	Includes bibliographical references === The synthesis and characterization of monomeric and dimeric salicylaldimine water-soluble ligands is discussed. The salicylaldimine ligands (2.3-2.10) were synthesised via Schiff base condensation reactions of various amines with water-soluble sulfonated salicylaldehydes (2.1 and 2.2). The ligands were characterized using various analytical and spectroscopic techniques. Complexation reactions of these water-soluble ligands (2.3-2.10) with [Rh(COD)Cl]2 gave the corresponding water-soluble mononuclear (2.11-2.14) and binuclear (2.15-2.18) Rh(I) complexes. All the complexes were characterized using nuclear magnetic resonance spectroscopy, infrared spectroscopy, single crystal X-ray diffraction (for complex 2.14), mass spectrometry, elemental analysis and melting point determinations.
author2	Smith, Gregory S
author_facet	Smith, Gregory S Matsinha, Leah Charlie
author	Matsinha, Leah Charlie
author_sort	Matsinha, Leah Charlie
title	Aqueous phase catalysis using mono- and bimetallic transition metal complexes
title_short	Aqueous phase catalysis using mono- and bimetallic transition metal complexes
title_full	Aqueous phase catalysis using mono- and bimetallic transition metal complexes
title_fullStr	Aqueous phase catalysis using mono- and bimetallic transition metal complexes
title_full_unstemmed	Aqueous phase catalysis using mono- and bimetallic transition metal complexes
title_sort	aqueous phase catalysis using mono- and bimetallic transition metal complexes
publisher	University of Cape Town
publishDate	2016
url	http://hdl.handle.net/11427/16704
work_keys_str_mv	AT matsinhaleahcharlie aqueousphasecatalysisusingmonoandbimetallictransitionmetalcomplexes
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Aqueous phase catalysis using mono- and bimetallic transition metal complexes

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