Discrete sacrificial anodes and their use in service life extension of chloride contaminated reinforced concrete structures

Includes bibliographical references. === There is an urgent need for economic and technically sound concrete repair technologies in South Africa as the number of deteriorating RC structures needing repair is increasing. Currently, the South African concrete repair industry mainly relies on the appli...

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Bibliographic Details
Main Author: Arito, Philemon
Other Authors: Beushausen, Hans-Dieter
Format: Dissertation
Language:English
Published: University of Cape Town 2015
Subjects:
Online Access:http://hdl.handle.net/11427/14797
Description
Summary:Includes bibliographical references. === There is an urgent need for economic and technically sound concrete repair technologies in South Africa as the number of deteriorating RC structures needing repair is increasing. Currently, the South African concrete repair industry mainly relies on the application of patch repairs and corrosion inhibitors while other potentially successful methods such as sacrificial anodes are rarely applied. Sacrificial anode cathodic protection (SACP) systems use metals that are higher than steel in the electrochemical series. These metals corrode preferentially to steel thereby supplying electrons to the cathodic steel surface. Common SACP systems include discrete zinc anodes installed in slots or drilled holes, non -structural jacket encasements, and overlays made from expanded zinc mesh or any other convenient form. The effectiveness of discrete SACP systems in service life extension of chloride contaminated RC slabs has been investigated in this study. Similarly, the extent to which discrete sacrificial anodes can be used to extend the service life of corroding chloride contaminated RC structures has been assessed through an extensive review of literature a s well as laboratory experiments on corroding chloride contaminated RC slabs . This study evaluates the performance of discrete SACP systems with respect to binder type, corrosion rate and the level of chloride contamination with an objective of developing guidelines for rational concrete repair when using SACP systems to repair RC structures that are deteriorating from corrosion of reinforcing steel in South Africa. Eight slabs were investigated. Four slabs were cast using 100% PC CEM 1, 42.5N while the other four were cast using a blend of 70/30 PC CEM 1, 42.5N/FA. Each slab comprised two portions: one half of each slab was cast using concrete that was admixed with 0.6% chloride by mass of binder while the other half was cast using concrete that was admixed with 1.8% chloride by mass of binder. The corrosion in the slabs was induced and accelerated using direct anodic current. The SACP system that was used in this study comprised discrete zinc disks put in a cylinder of a proprietary high alkaline mortar. The se anodes were installed in 1 0 0 x 10 0 x 60 mm deep cavities that had been made in concrete. The anodes were connected to the reinforcement cage using tie wires and thereafter backfilled with a repair mortar. The cavities in which the anodes were installed were arranged in a square grid of 450 x 450 mm. The corrosion rate and half-cell potential of the steel as well as the resistivity of concrete in the slabs were monitored over a duration of five month s. The discrete SACP system that has been investigated in this study can increase the service life of chloride contaminated RC structures that are deteriorating as a result of rebar corrosion. The discrete anodes reduced the corrosion rate of steel in the test slabs. The percentage reduction in the average corrosion rate was higher within the slabs that were cast using 100% PC CEM 1, 42.5N than in the slabs that were cast using a blend of 70/30 PC CEM 1, 42.5N/FA. The reduction in average corrosion rate within the slabs cast using 100% PC CEM 1, 42.5N ranged between 45-95%. Similarly, the reduction in the average corrosion rate of within the slabs that were cast using a blend of 70/30 PC CEM, 42.5N 1/ FA ranged between 54-75%. Throughout the test specimens, the portions of the slabs that was admixed with 0.6% chloride by mass of binder exhibited superior performance. These portions (admixed with 0.6% chloride by mass of binder) experienced the greatest reduction in average corrosion rate as well as the greatest shift in average half -cell potential towards values that are more negative. Finally, in order to achieve the long-term objective of increasing the service life of RC structures that are deteriorating as a result of rebar corrosion, lo ng-term studies ought to be undertaken to ascertain, with surety, the effectiveness of discrete SACP systems in corroding structures.