Ligand substitution effects in uranyl ο-hydroxyarylcarbonyl complexes

Twenty-two base adducts of uranyl o-hydroxyarylcarbonyl complexes [UO2L2B] (L = o-hydroxyarylcarbonyl compound, B = H2O, pyridine, pyridine N-oxide) have been prepared. Pure field substituent parameters are used to derive a quantitative order of the electronic effects of the chelate ring substituent...

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Main Author:	Haigh, J M
Format:	Others
Language:	English
Published:	1974
Online Access:	http://hdl.handle.net/10962/d1006075

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spelling	ndltd-netd.ac.za-oai-union.ndltd.org-rhodes-vital-63722018-03-06T03:55:31ZLigand substitution effects in uranyl ο-hydroxyarylcarbonyl complexesHaigh, J MTwenty-two base adducts of uranyl o-hydroxyarylcarbonyl complexes [UO2L2B] (L = o-hydroxyarylcarbonyl compound, B = H2O, pyridine, pyridine N-oxide) have been prepared. Pure field substituent parameters are used to derive a quantitative order of the electronic effects of the chelate ring substituents. Values of v(U=O) correlate well with these values. Evidence is cited suggesting almost complete non-aromaticity of the chelate ring, and the transmission of the electronic effects of the chelate ring substituent through the uranium atom in the pyridine and pyridine N-oxide base adducts.1974textArticle8 pagespdfvital:6372http://hdl.handle.net/10962/d1006075English
collection	NDLTD
language	English
format	Others
sources	NDLTD
description	Twenty-two base adducts of uranyl o-hydroxyarylcarbonyl complexes [UO2L2B] (L = o-hydroxyarylcarbonyl compound, B = H2O, pyridine, pyridine N-oxide) have been prepared. Pure field substituent parameters are used to derive a quantitative order of the electronic effects of the chelate ring substituents. Values of v(U=O) correlate well with these values. Evidence is cited suggesting almost complete non-aromaticity of the chelate ring, and the transmission of the electronic effects of the chelate ring substituent through the uranium atom in the pyridine and pyridine N-oxide base adducts.
author	Haigh, J M
spellingShingle	Haigh, J M Ligand substitution effects in uranyl ο-hydroxyarylcarbonyl complexes
author_facet	Haigh, J M
author_sort	Haigh, J M
title	Ligand substitution effects in uranyl ο-hydroxyarylcarbonyl complexes
title_short	Ligand substitution effects in uranyl ο-hydroxyarylcarbonyl complexes
title_full	Ligand substitution effects in uranyl ο-hydroxyarylcarbonyl complexes
title_fullStr	Ligand substitution effects in uranyl ο-hydroxyarylcarbonyl complexes
title_full_unstemmed	Ligand substitution effects in uranyl ο-hydroxyarylcarbonyl complexes
title_sort	ligand substitution effects in uranyl ο-hydroxyarylcarbonyl complexes
publishDate	1974
url	http://hdl.handle.net/10962/d1006075
work_keys_str_mv	AT haighjm ligandsubstitutioneffectsinuranylohydroxyarylcarbonylcomplexes
_version_	1718615549841244160

Ligand substitution effects in uranyl ο-hydroxyarylcarbonyl complexes

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