Unexpected transformations of 3-(bromoacetyl)coumarin provides new evidence for the mechanism of thiol mediated dehalogenation of α-halocarbonyls
publisher version === The mechanism for the thiol mediated dehalogenation of α-halogenated carbonyls has remained an unresolved problem, despite its ongoing application in synthetic organic chemistry. Nakamura and co-workers first proposed that net dehalogenation occurs via sequential nucleophilic s...
| Main Authors: | , , |
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| Format: | Others |
| Language: | English |
| Published: |
2017
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| Online Access: | http://hdl.handle.net/10962/66200 https://doi.org/10.1016/j.tetlet.2017.01.082 |