Toward lanthanide containing coordination polymers and nanomaterials

• Other Authors: Greig, Natalie E.
• Format: Others
• Language: English
• Published: Florida Atlantic University
• Subjects: Metallic composites > Speciation; Lanthanide shift reagents; Rare earth metals catalysts; Nanostructured materials
• Online Access: http://purl.flvc.org/FAU/3358558

The focus of this thesis is to develop lanthanide (Ln) luminescent materials through the exploration of coordination polymers and nanomaterials. Herein, dimethyl-3,4- furanedicarboxylate acid undergoes hydrolysis under hydrothermal conditions to form coordination polymers with lanthanide ions. The resulting coordination polymers exhibited luminescent properties, with quantum yields and lifetimes for the Eu-and Tb-CP of 1.14+-0.32% and 0.387=-0.0001 mx, and 3.33=-0.82% and 0.769=-0.006 ms, respectively. While the incorporation of lanthanides was not achieved in this work, progress toward the production of pure phase InP in the nanoregime has been made, using a low-cost, hydrothermal method. Through SEM and PXRD conflict, it is believed that pure INP particles with a size range of 58-81 nm were successfully synthesized. === by Natalie E. Greig. === Thesis (M.S.)--Florida Atlantic University, 2012. === Includes bibliography. === Mode of access: World Wide Web. === System requirements: Adobe Reader.