Synthesis, structure, and reactivity of group 4 metal-carboryne complexes.
A series of group 4 metal-carboryne complexes were synthesized by the reaction of Li2C2B10H10 with dichloro group 4 metal complexes. Reaction of (eta2-C 2B10H10)ZrCl2(THF)3 with 2 equiv of [MeC(NCy)2]Li or [nPr 2NC(NPri)2]Li also effectively yielded the corresponding group-4-metal-carboryne complexe...
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| Format: | Others |
| Language: | English Chinese |
| Published: |
2010
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| Online Access: | http://library.cuhk.edu.hk/record=b6074908 http://repository.lib.cuhk.edu.hk/en/item/cuhk-344541 |