Theory of pure vibrational transitions of ¹⁶O₂ in solid parahydrogen.

• Other Authors: Yang, Mei.
• Format: Others
• Language: English; Chinese
• Published: 2010
• Subjects: Oxygen; High resolution spectroscopy; Solid hydrogen; Chemical reactions
• Online Access: http://library.cuhk.edu.hk/record=b5894352; http://repository.lib.cuhk.edu.hk/en/item/cuhk-327203

Yang, Mei. === Thesis (M.Phil.)--Chinese University of Hong Kong, 2010. === Includes bibliographical references (leaves 73-75). === Abstracts in English and Chinese. === THESIS COMMITTEE --- p.II === ABSTRACT --- p.III === 中文摘要 --- p.V === ACKNOWLEDGENTS --- p.VI === TABLE OF CONTENTS --- p.VII === LIST OF FIGURES --- p.IX === LIST OF TABLES --- p.X === Chapter CHAPTER 1 --- INTRODUCTION --- p.1 === Chapter 1.1 --- Matrix isolation spectroscopy --- p.1 === Chapter 1.2 --- Properties of Molecular Hydrogen： A Review --- p.3 === Chapter 1.3 --- Unique properties of solid hydrogen --- p.8 === Chapter CHAPTER 2 --- THEORETICAL BACKGROUND --- p.12 === Chapter 2.1 --- Multipole moments of molecules --- p.12 === Chapter 2.2 --- POLARIZABILITY --- p.14 === Chapter 2.3 --- Pair intermolecular potential --- p.15 === Chapter 2.4 --- Multipole induced transitions --- p.20 === Chapter CHAPTER 3 --- THEORY OF MATRIX ISOLATED 02 IN SOLID PARAHYDROGEN --- p.24 === Chapter 3.1 --- Structural properties of 1602 --- p.24 === Chapter 3.1.1 --- Group theoretical treatment --- p.24 === Chapter 3.1.2 --- Rovibrational wavefunctions and energies --- p.26 === Chapter 3.2 --- O2 isolated in hcp crystal field of parahydrogen --- p.31 === Chapter 3.2.1 --- Group theory --- p.31 === Chapter 3.2.2 --- Crystal field splitting --- p.37 === Chapter 3.2.3 --- Effect of quadrupolar induction --- p.42 === Chapter 3.2.4 --- Pure vibrational transitions --- p.42 === Chapter 3.2.5 --- Calculation of quadrupole matrix elements --- p.47 === Chapter CHAPTER 4 --- RESULTS AND DISCUSSION --- p.54 === Chapter 4.1 --- Results --- p.55 === Chapter 4.1.1 --- Effect of quadrupolar induction --- p.55 === Chapter 4.1.2 --- Crystal field splitting of rovibrational levels of O2 in p-H2 matrix --- p.57 === Chapter 4.1.3 --- Predicted pure vibrational spectrum --- p.64 === Chapter 4.2 --- Discussion and Conclusion --- p.67 === REFERENCE --- p.73