Syntheses, structures and reactivities of bis(thiophosphinoyl) metal complexes.

• Other Authors: Wan, Chi Ling.
• Format: Others
• Language: English; Chinese
• Published: 2009
• Subjects: Metal complexes > Synthesis; Thiophosphates; Ligands; Chemical structure
• Online Access: http://library.cuhk.edu.hk/record=b5893996; http://repository.lib.cuhk.edu.hk/en/item/cuhk-326777

Wan, Chi Ling. === Thesis (M.Phil.)--Chinese University of Hong Kong, 2009. === Includes bibliographical references. === Abstracts in English and Chinese. === Table of Contents --- p.vi === Acknowledgement --- p.i === Abstract --- p.ii === 摘要 --- p.iv === List of Compounds Synthesized in This Work --- p.x === Abbreviation --- p.xi === Chapter Chapter 1 --- Synthesis of Group 1 and 2 Metal Bis(thiophosphinoyl) Complexes === Chapter 1.1 --- Introduction --- p.1 === Chapter 1.1.1 --- General Aspects of Thiophosphinoyl Ligands --- p.1 === Chapter 1.1.2 --- General Aspects of Group 1 and 2 Thiophosphinoyl Metal Complexes --- p.6 === Chapter 1.1.3 --- Objectives of This Work --- p.10 === Chapter 1.2 --- Results and Discussion --- p.11 === Chapter 1.2.1.1 --- Synthesis of Monoanionic Bis(thiophosphinoyl) Lithium Complex --- p.11 === Chapter 1.2.1.2 --- Spectroscopic Properties of 42 --- p.11 === Chapter 1.2.1.3 --- Molecular Structure of [Li{(S=PPh2)CH}(THF)(Et20)] (42) --- p.12 === Chapter 1.2.2.1 --- Synthesis of Dianionic Bis(thiophosphinoyl) Magnesium Complex --- p.14 === Chapter 1.2.2.2 --- Spectroscopic Properties of 43 --- p.14 === Chapter 1.2.2.3 --- Molecular Structure of [MgC(PPh2=S)(THF)]2.2THF (43) --- p.15 === Chapter 1.3 --- Experimental for Chapter 1 --- p.17 === Chapter 1.4 --- References for Chapter 1 --- p.19 === Chapter Chapter 2 --- Synthesis and Reactivity of Group 14 Metal Bis(thiophosphinoyl) Complexes === Chapter 2.1 --- Introduction --- p.24 === Chapter 2.1.1 --- General Aspects of Low Valent Group 14 Organometallic Compounds --- p.24 === Chapter 2.2 --- Results and Discussion --- p.32 === Chapter 2.2.1.1 --- "Synthesis of 1,3-Distannacyclobutane and 1,3-Diplumbacyclobutane" --- p.32 === Chapter 2.2.1.2 --- Spectroscopic Properties of 74 and 75 --- p.33 === Chapter 2.2.1.3 --- Molecular Structures of [Sn{u2-C(Ph2P=S)2}]2.THF (74) and [Pb{u2-C(Ph2P=S)2}]2.THF(75) --- p.34 === Chapter 2.2.2.1 --- "Reaction of 1,3-Diplumbacyclobutane with Chalcogens" --- p.38 === Chapter 2.2.2.2 --- Spectroscopic Properties of 78 and 79 --- p.39 === Chapter 2.2.2.3 --- "Molecular Structures of [PbE{C(PPh2=S)2}] (E = S (78),Se (79))" --- p.39 === Chapter 2.2.3.1 --- Synthesis of Chlorogermylene and Chlorostannylene --- p.44 === Chapter 2.2.3.2 --- Spectroscopic Properties of 80 and 81 --- p.44 === Chapter 2.2.3.3 --- "Molecular Structures of [MCl{CH(PPh2=S)2}] (M = Ge (80),Sn (81))" --- p.45 === Chapter 2.2.4.1 --- Reaction of Chlorogermylene with Chalcogens --- p.49 === Chapter 2.2.4.2 --- Spectroscopic Properties of 82 --- p.50 === Chapter 2.2.4.3 --- Molecular Structure of [GeCl{CH(PPh2=S)2}(u-S)]2.4THF (82) --- p.51 === Chapter 2.2.4.4 --- Reaction of Chlorostannylene with Pb{N(SiMe3)2}2 --- p.53 === Chapter 2.3 --- Experimental for Chapter 2 --- p.54 === Chapter 2.4 --- References for Chapter 2 --- p.60 === Chapter Chapter 3 --- Synthesis of Group 13 Metal Bis(thiophosphinoyl) Complexes === Chapter 3.1 --- Introduction --- p.65 === Chapter 3.1.1 --- General Aspects of Group 13 Organometallic Chemistry --- p.65 === Chapter 3.1.2 --- General Aspects of Group 13 Metal Complexes Bearing Phosphoranoimine or Phosphoranosulfide Ligands --- p.67 === Chapter 3.2 --- Results and Discussions --- p.72 === Chapter 3.2.1 --- Synthesis of Group 13 Metal Bis(thiophosphinoyl) Complexes --- p.72 === Chapter 3.2.2 --- Spectroscopic Properties of 108-110 --- p.72 === Chapter 3.2.3 --- "Molecular Structures of [MCl{C(PPh2=S)2}]2 (M = A1 (108),Ga (109), In (110))" --- p.73 === Chapter 3.3 --- Experimental for Chapter 3 --- p.79 === Chapter 3.4 --- References for Chapter 3 --- p.82 === Chapter Chapter 4 --- Synthesis of Group 4 Metal Bis(thiophosphinoyl) Complexes === Chapter 4.1 --- Introduction --- p.86 === Chapter 4.1.1 --- General Aspects of Group 4 Early Transition Metal Complexes --- p.86 === Chapter 4.2 --- Results and Discussion --- p.92 === Chapter 4.2.1 --- Synthesis of Group 4 Metal Bis(thiophosphinoyl) Complexes --- p.92 === Chapter 4.2.2 --- Spectroscopic Properties of 125-128 --- p.93 === Chapter 4.2.3 --- Molecular Structures of [Hf(NMe2)3{CH(PPh2=S)2}] (126) --- p.94 === Chapter 4.3 --- Experimental for Chapter 4 --- p.97 === Chapter 4.4 --- References for Chapter 4 --- p.100 === Appendix I === Chapter A. --- General Procedures --- p.104 === Chapter B. --- Physical and Analytical Measurements --- p.104 === Chapter C. --- X-ray Crystallographic Determination --- p.105 === Appendix II === "Table A.1. Selected Crystallographic Data for Compounds 42,43,74 and 75" --- p.108 === Table A.2. Selected Crystallographic Data for Compounds 77-80 --- p.109 === "Table A.3. Selected Crystallographic Data for Compounds 81,108-110 and 126" --- p.110 === Appendix III === Chapter A. --- Future Work --- p.111