Competitive aromatic carbon fluorine bond activation and carbon hydrogen bond activation of fluorobenzenes by rhodium (III) porphyrins.
Lee, Man Ho. === Thesis submitted in: October 2008. === Thesis (M.Phil.)--Chinese University of Hong Kong, 2009. === Includes bibliographical references (leaves 78-83). === Abstracts in English and Chinese. === Table of Contents --- p.ii === Acknowledgements --- p.iv === Abbreviations --- p.v ===...
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| Format: | Others |
| Language: | English Chinese |
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2009
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| Online Access: | http://library.cuhk.edu.hk/record=b5893878 http://repository.lib.cuhk.edu.hk/en/item/cuhk-326529 |
| Summary: | Lee, Man Ho. === Thesis submitted in: October 2008. === Thesis (M.Phil.)--Chinese University of Hong Kong, 2009. === Includes bibliographical references (leaves 78-83). === Abstracts in English and Chinese. === Table of Contents --- p.ii === Acknowledgements --- p.iv === Abbreviations --- p.v === Abstract --- p.vi === Chapter Chapter 1 --- Introduction === Chapter 1.1 --- Definition of Aromatic Bond Activation --- p.1 === Chapter 1.2 --- Application of Aromatic Carbon Fluorine Bond Activation --- p.1 === Chapter 1.3 --- Mechanistic Schemes Involved in Aromatic Bond Activation --- p.2 === Chapter 1.4 --- Difficulties in Aromatic Bond Activation --- p.7 === Chapter 1.5 --- Competitive Bond Activations --- p.20 === Chapter 1.6 --- Structural Features of Rhodium Porphyrins --- p.27 === Chapter 1.7 --- Objective of the Work --- p.28 === Chapter Chapter 2 --- Competitive C-F and C-H Activation of Fluorobenzenes by Rhodium(III) Porphyrins === Chapter 2.1 --- C-F Activation of Fluorobenzene by Rhodium(III) Porphyrins --- p.29 === Chapter 2.2 --- Preparation of Starting Materials --- p.29 === Chapter 2.3 --- Base Effect of CFA --- p.30 === Chapter 2.4 --- Solvent Effect of CFA --- p.32 === Chapter 2.5 --- Temperature Effect of CFA Reaction --- p.34 === Chapter 2.6 --- Activations of Fluorobenzene --- p.35 === Chapter 2.7 --- Electronic Effect of Carbon-Fluorine Bond Activations --- p.38 === Chapter 2.8 --- Preliminary Mechanistic Studies --- p.39 === Chapter 2.9 --- Proposed C-F Activation Mechanism --- p.44 === Chapter 2.10 --- Proposed C-H Activation Mechanism --- p.48 === Chapter 2.11 --- Summary --- p.51 === Chapter Chapter 3 --- Experimental Section --- p.56 === References --- p.78 === Table of Content of Appendix --- p.83 === Appendix I Crystal Data and Processing Parameters --- p.85 === Appendix II Spectra --- p.91 |
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