Synthesis of bis(phosphoranoimido)metal complexes.

• Other Authors: Sze, Wing Yin.
• Format: Others
• Language: English; Chinese
• Published: 2006
• Subjects: Transition metal complexes; Phosphorus compounds
• Online Access: http://library.cuhk.edu.hk/record=b5892844; http://repository.lib.cuhk.edu.hk/en/item/cuhk-325475

Sze Wing Yin. === Thesis submitted in: November 2005. === Thesis (M.Phil.)--Chinese University of Hong Kong, 2006. === Includes bibliographical references. === Abstracts in English and Chinese. === Table of Contents --- p.vi === Acknowledgements --- p.i === Abstract --- p.ii === 摘要 --- p.iv === List of Compounds Synthesized --- p.x === Abbreviation --- p.xi === Chapter Chapter 1 --- Syntheses and Characterization of Bis(phosphoranoimido)lithium and Late Transition Metal Complexes === Chapter 1.1 --- Introduction --- p.1 === Chapter 1.1.1 --- A General Review of Bis(Phosphoranoimido) Ligands --- p.1 === Chapter 1.1.2 --- Synthesis of Bis(Phosphoranoimido)metal Complexes --- p.8 === Chapter 1.2 --- Objectives --- p.13 === Chapter 1.3 --- Results and Discussion --- p.14 === Chapter 1.3.1.1 --- "Synthesis of Bis(Phosphoranoimido)lithium complexes [Li{{(Me3SiNPR2CH)(Me3SiN=PR2CH2)}C5H3N-2，6} (R = Ph, 36; R = Pr', 37)]" --- p.14 === Chapter 1.3.1.2 --- Spectroscopic Properties of Complexes 36 and 37 --- p.14 === Chapter 1.3.1.3 --- "Molecular Structures of [Li{{(Me3SiNPR2CH)- (Me3SiN=PR2CH2)}C5H3N-2,6} (R = Ph, 36; R = Pr', 37)]" --- p.16 === Chapter 1.3.2.1 --- Synthesis and Characterization of Bis(Phosphoranoimido)transition Metal Complexes --- p.21 === Chapter 1.3.2.2 --- Spectroscopic Properties of 38 - 41 --- p.21 === Chapter 1.3.2.3 --- "Molecular Structures of [MCI {{(Me3SiNPPh2CH)- (Me3SiN=PPh2CH2)}C5H3N-2,6}] (M = Co, 38; Mn, 39)， [MnCl{{(Me3SiNPPri2CH)(Me3SiN=PPri2CH2)}C5H3N-2，6}] (41)" --- p.22 === Chapter 1.4 --- Experimental Section --- p.31 === Chapter 1.5 --- References for Chapter 1 --- p.36 === Chapter Chapter 2 --- Syntheses and Characterization of Bis(phosphoranoimido)zirconium(IV) Complex === Chapter 2.1 --- Introduction --- p.39 === Chapter 2.1.1 --- General Aspects of Group 4 Metal Complexes --- p.39 === Chapter 2.2 --- Results and Discussion --- p.44 === Chapter 2.2.1 --- "Synthesis and Characterization of Bis(phosphoranoimido)zirconium(IV) Complex [Zr{(Me3SiNPPh2C)(Me3SiN=PPh2CH2)C5H3N-2,6}(NMe2)2] (46)" --- p.44 === Chapter 2.2.2 --- Reaction of Bis(phosphoranoimido)zirconium(IV) Complex (46) with HC1 --- p.45 === Chapter 2.2.3 --- Spectroscopic Properties of Complex 46 --- p.45 === Chapter 2.2.4 --- Molecular Structure of [Zr{(Me3SiNPR2C)- (Me3SiN=PR2CH2)5H3N-2，6}(NMe2)2] (46) --- p.46 === Chapter 2.3 --- Experimental Section --- p.51 === Chapter 2.4 --- References for Chapter 2 --- p.52 === Chapter Chapter 3 --- Syntheses and Characterization of Bis(phosphoranoimido)samarium(III) Complexes === Chapter 3.1 --- Introduction --- p.54 === Chapter 3.1.1 --- A General Review of Lanthanide Complexes --- p.54 === Chapter 3.1.2 --- General Aspect of Bis(phosphoranoimido)lanthanide Metal Complexes --- p.58 === Chapter 3.1.3 --- Synthesis and Structure of Bis(phosphoranoimido)dilithium Complex --- p.60 === Chapter 3.2 --- Results and Discussion --- p.63 === Chapter 3.2.1 --- Synthesis and Characterization of Bis(phosphoranoimido)samarium(III) Complexes --- p.63 === Chapter 3.2.2 --- Spectroscopic Properties of 56 and 57 --- p.65 === Chapter 3.2.3 --- "Molecular Structures of [Sm {{(Me3SiNPPh2CH)2} - C5H3N-2，6}(μ-Cl2)Li(THF)2] (56) and [Sm{{(Me3SiNPPri2CH)2}C5H3N-2,6}2(μ-Cl)]2 (57)" --- p.65 === Chapter 3.3 --- Experimental Section --- p.72 === Chapter 3.4 --- References for Chapter 3 --- p.74 === Appendix I === Chapter A. --- General Procedures --- p.77 === Chapter B. --- Physical and Analytical Measurements --- p.77 === Appendix II === Table A.1. Selected Crystallographic Data for Compounds 36，37 and 38 --- p.80 === Table A.2. Selected Crystallographic Data for Compounds 39，41 and 46 --- p.81 === Table A.3. Selected Crystallographic Data for Compounds 56 and 57 --- p.82