Part I, optimization of palladium catalyzed phosphination: Part II, syntheses of optically active As,N ligands and their metal complexes.

• Other Authors: Yu, Michael.
• Format: Others
• Language: English; Chinese
• Published: 2004
• Subjects: Phosphine; Palladium catalysts; Ligands > Synthesis
• Online Access: http://library.cuhk.edu.hk/record=b5892116; http://repository.lib.cuhk.edu.hk/en/item/cuhk-324771

Yu Michael. === Thesis submitted in: July 2003. === Thesis (M.Phil.)--Chinese University of Hong Kong, 2004. === Includes bibliographical references (leaves 57-63). === Abstracts in English and Chinese. === Table of Contents --- p.i === Acknowledgments --- p.iii === Abbreviations --- p.iv === Abstract --- p.v === Chapter Part I - --- Optimization of Palladium Catalyzed Phosphination === Chapter Chapter 1 --- General Introduction === Chapter 1.1 --- Background of Phosphine Synthesis --- p.1 === Chapter 1.2 --- Preparation of Phosphines --- p.4 === Chapter Chapter 2 --- Optimization of Phosphination of Aryl Bromides === Chapter 2.1 --- Additive Effect in Phosphination of Aryl Bromides --- p.14 === Chapter 2.2 --- Iodide Effect in Phosphination of Aryl Triflate --- p.25 === Chapter 2.3 --- Low Temperature Phosphination --- p.27 === Chapter 2.4 --- Conclusion --- p.29 === Chapter Part II - --- Synthesis of Optically Active As，N Ligands and Their Metal Complexes === Chapter Chapter 1 --- 3.1 Introduction --- p.30 === Chapter Chapter 2 --- Synthesis of Optically Active As，N Ligands and Their Metal Complexes === Chapter 4.1 --- "Synthesis of As,N Oxazolines" --- p.39 === Chapter 4.2 --- "Synthesis of As,N Oxazoline Transition Metal Complexes" --- p.41 === Chapter 4.3 --- Conclusion --- p.44 === Experimental --- p.45 === References --- p.57 === Appendix --- p.64