Syntheses and structures of copper and zinc complexes with N₃O donor ligands.
by Chan Sau Han. === Thesis (M.Phil.)--Chinese University of Hong Kong, 2001. === Includes bibliographical references. === Abstracts in English and Chinese. === ABSTRACT --- p.i === 摘要 --- p.ii === ACKNOWLEDGMENT --- p.iii === CONTENTS --- p.iv === ABBREVIATIONS --- p.vi === Chapter CHAPTER 1 -...
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| Format: | Others |
| Language: | English Chinese |
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2001
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| Online Access: | http://library.cuhk.edu.hk/record=b5895872 http://repository.lib.cuhk.edu.hk/en/item/cuhk-323519 |
| Summary: | by Chan Sau Han. === Thesis (M.Phil.)--Chinese University of Hong Kong, 2001. === Includes bibliographical references. === Abstracts in English and Chinese. === ABSTRACT --- p.i === 摘要 --- p.ii === ACKNOWLEDGMENT --- p.iii === CONTENTS --- p.iv === ABBREVIATIONS --- p.vi === Chapter CHAPTER 1 --- General Introduction === Chapter 1-A. --- Role of Copper in Biology --- p.1 === Chapter 1-B. --- A Brief Review on Radical Copper Proteins --- p.4 === Chapter 1-C. --- Objectives of This Work --- p.12 === Chapter 1-D. --- References --- p.13 === Chapter CHAPTER 2 --- Copper(II) and Zinc(II) Complexes containing N3O Tetradentate Ligands === Chapter 2-A. --- Introduction Results and Discussion --- p.14 === Chapter 2-B. --- Preparation of Tetradentate Ligands and Complexes --- p.27 === Chapter 2-C. --- Characterization --- p.36 === Chapter 2-D. --- Generation of Metal Phenoxyl Radical Species --- p.51 === Chapter 2-E. --- Summary --- p.57 === Chapter 2-F. --- References --- p.59 === Chapter CHAPTER 3 --- Copper(I) Complexes with N30 Tetradentate Ligands === Chapter 3-A. --- Introduction Results and Discussion --- p.62 === Chapter 3-B. --- Preparation of Copper(I) Complexes with N30 Tetradentate Ligands --- p.75 === Chapter 3-C. --- Characterization --- p.79 === Chapter 3-D. --- Reactivities of 86，87 and 88 toward Dioxygen --- p.88 === Chapter 3-E. --- Summary --- p.93 === Chapter 3-F. --- References --- p.94 === Chapter CHAPTER 4 --- Experimental Sections === Chapter 4-A. --- General Preparations and Physical Measurements --- p.97 === Chapter 4-B. --- Compounds Described in Chapter2 --- p.99 === Chapter 4-C. --- Compounds Described in Chapter3 --- p.113 === Chapter 4-D. --- Oxo-Transfer to Triphenylphosphine as Described in Chapter3 --- p.117 === Chapter 4-E. --- References --- p.119 === Chapter APPENDIX A --- 1H and13 C̐ưث1H ̐ưحNMR Spectra === Chapter A-1. --- Compounds Described in Chapter2 --- p.120 === Chapter A-2. --- Compounds Described in Chapter3 --- p.127 === Chapter APPENDIX B --- Crystallographic Data === Chapter B-1. --- X-ray Crystal Structure Data for Complexes in Chapter2 --- p.131 === Chapter B-2. --- X-ray Crystal Structure Data for Complexes in Chapter3 --- p.133 === Chapter APPENDIX C --- GC-MS Spectra === Chapter C-1. --- GC-MS Spectra for Standard Samples --- p.134 === Chapter C-2. --- GC-MS Spectra for the Reactions with Triphenylphosphine Described in Chapter3 --- p.136 |
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