Synthesis, structures and reactivities of low-valent late transition metal amides.
Chung Hei Lam. === Thesis (M.Phil.)--Chinese University of Hong Kong, 2001. === Includes bibliographical references. === Abstracts in English and Chinese. === Table of Contents --- p.i === Acknowledgements --- p.iv === Abstracts --- p.v === 摘要 --- p.vii === List of Compounds --- p.ix === List o...
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| Format: | Others |
| Language: | English Chinese |
| Published: |
2001
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| Subjects: | |
| Online Access: | http://library.cuhk.edu.hk/record=b5895885 http://repository.lib.cuhk.edu.hk/en/item/cuhk-323410 |
| Summary: | Chung Hei Lam. === Thesis (M.Phil.)--Chinese University of Hong Kong, 2001. === Includes bibliographical references. === Abstracts in English and Chinese. === Table of Contents --- p.i === Acknowledgements --- p.iv === Abstracts --- p.v === 摘要 --- p.vii === List of Compounds --- p.ix === List of Tables --- p.xii === List of Figures --- p.xiv === Abbreviations --- p.xv === Chapter CHAPTER 1. --- SYNTHESIS OF LATE TRANSITION METAL AMIDES === Chapter 1.1 --- GENERAL BACKGROUND --- p.1 === Chapter 1.2 --- PREPARATIONS OF LATE TRANSITION METAL AMIDES --- p.2 === Chapter 1.3 --- OBJECTIVES OF THIS WORK --- p.3 === Chapter 1.4 --- REFERENCES FOR CHAPTER1 --- p.5 === Chapter CHAPTER 2. --- "SYNTHESIS, STRUCTURES AND REACTIVITIES OF IRON(II) AND COBALT(II) AMIDES" === Chapter 2.1 --- INTRODUCTION --- p.7 === Chapter 2.1.1 --- A General Review on Iron(II) and Cobalt (II) Amides --- p.7 === Chapter 2.1.2 --- A General Review on Iron(II) and Cobalt(II) Thiolates --- p.9 === Chapter 2.1.3 --- A General Review on Iron(II) and Cobalt(II) Alkoxides and Aryloxides --- p.11 === Chapter 2.2 --- RESULTS AND DISCUSSION --- p.13 === Chapter 2.2.1 --- Synthesis of the Ligand Precursor LH (1) and the Corresponding Lithium Reagents [Li(L)(TMEDA)] (2) and LiL (3) --- p.13 === Chapter 2.2.2 --- Synthesis´ة Structures and Reactivities of Mononuclear Iron(II) and Cobalt(II) Amides --- p.14 === Chapter 2.2.2.1 --- Synthesis of Mononuclear Iron(II) and Cobalt(II) Amides --- p.14 === Chapter 2.2.2.2 --- Reactions of Compound 4 with ArMe OH and ArSH --- p.18 === Chapter 2.2.2.3 --- Physical Characterization of Compounds 4-6 --- p.19 === Chapter 2.2.2.4 --- Molecular Structures of Compounds 4-6 --- p.20 === Chapter 2.2.3 --- "Synthesis, Structures and Reactivities of Binuclear Iron(II) and Cobalt (II) Amides" --- p.31 === Chapter 2.2.3.1 --- Synthesis of Binuclear Iron(II) and Cobalt(II) Amides --- p.31 === Chapter 2.2.3.2 --- Reactions of Compounds 7 and 8 with Protic Reagents --- p.33 === Chapter 2.2.3.3 --- "Attempted Reactions of Compounds 7 and 8 with 3,5-di-tert- butylcatechol" --- p.35 === Chapter 2.2.3.4 --- Physical Characterization of Compounds 7-14 --- p.35 === Chapter 2.2.3.5 --- Molecular Structures of Compounds 7-10 and 13-14 --- p.38 === Chapter 2.3 --- EXPERIMENTALS FOR CHAPTER 2 --- p.57 === Chapter 2.4 --- REFERENCES FOR CHAPTER 2 --- p.64 === Chapter CHAPTER 3. --- SYNTHESIS AND STRUCTURES OF MANGANESE(II) AMIDES === Chapter 3.1 --- INTRODUCTION --- p.68 === Chapter 3.2 --- RESULTS AND DISCUSSION --- p.70 === Chapter 3.2.1 --- Synthesis of Manganese(II) Amide --- p.70 === Chapter 3.2.2 --- Physical Characterization of Compound 15 --- p.72 === Chapter 3.2.3 --- Molecular Structure of Compound 15 --- p.73 === Chapter 3.3 --- EXPERIMENTALS FOR CHAPTER 3 --- p.78 === Chapter 3.4 --- REFERENCES FOR CHAPTER 3 --- p.79 === "APPENDIX 1 General Procedures, Physical Measurements and X-ray Structure Analysis" --- p.81 === APPENDIX 2 Table A-1. Selected crystallographic data for compounds 4-6. --- p.84 === Table A-2. Selected crystallographic data for compounds 7-10. --- p.85 === Table A-3. Selected crystallographic data for compounds 13-15 --- p.86 |
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