Synthesis of covalently-linked porphyrin-quinones and their metal complexes.

• Other Authors: Chan, Chi-shing.
• Format: Others
• Language: English
• Published: Chinese University of Hong Kong 1993
• Subjects: Porphyrins; Organometallic compounds
• Online Access: http://library.cuhk.edu.hk/record=b5887808; http://repository.lib.cuhk.edu.hk/en/item/cuhk-319168

by Chi-Shing Chan. === Thesis (M.Phil.)--Chinese University of Hong Kong, 1993. === Includes bibliographical references (leaves 62-65). === Acknowledgements --- p.i === Contents --- p.ii === Abbreviations --- p.iii === Abstract --- p.1 === Introduction --- p.2-8 === Synthetic Strategy --- p.9-12 === Results and Discussion === Chapter A. --- Synthesis of the aryl triflate substituted and aryl bromide substituted porphyrins --- p.13-15 === Chapter B. --- Synthesis of the (alkynyl)phenyl substituted porphyrins --- p.16-19 === Chapter C --- Benzannulation of Fischer carbene complexes with (alkynyl)phenyl substituted porphyrins --- p.20-23 === Chapter D. --- "Palladium-catalysed cross coupling reaction of 2,5-dimethoxyphenyl boronic acid with aryl triflate or aryl bromide substituted porphyrins" --- p.24-28 === Chapter E. --- Synthesis of the meso-tetrakis(benzoquinonyl) porphyrin --- p.29 === Chapter F. --- Metalation of the quinone-linked porphyrins --- p.30 === Chapter G. --- Preliminary study on the electrocatalytic activity of the quinone-linked metalloporphyrin complexes of cobalt and palladium for the electrochemical reduction of carbon dioxide --- p.31 === Conclusion --- p.32 === Experimental --- p.33-61 === References --- p.62-65 === List of spectra === Porphyrin aryl triflate4 --- p.66 === (Alkynyl)phenyl porphyrin 9 d --- p.67 === Tetra(quinonyl)phenyl porphyrin 12a --- p.68 === (Naphthoquinonyl)phenyl porphyrin 13b --- p.69 === "2,5 -dimethoxyphenyl boronic acid 16" --- p.70 === (Benzoquinonyl)phenyl porphyrin19 --- p.71 === Tetra(quinonyl)phenyl porphyrin 23 --- p.72