Effect of molecular structure on the rearrangements of some ethylene oxides
The BF₃:etherate catalysed reactions of a series of ethylene oxides contained in a 4-tert-butylcyclohexane system have been examined. Rearrangements of the epoxides to give carbonyl products have been explained in terms of discrete carbonium ion intermediates. The 4-tert-butylcyclohexanes (7,8) giv...
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| Language: | en |
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University of Canterbury. Chemistry
2013
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| Online Access: | http://hdl.handle.net/10092/8391 |