3d metal complexes with the perfluoro-tert-butoxide and perfluoropinacolate ligands: dioxygen reduction and intermolecular substrate oxidation
A CuI fully fluorinated O-donor monodentate alkoxide complex, K[Cu(OC4F9)2] (1), was previously shown to form a trinuclear copper–dioxygen species with a {Cu3(3-O)2} core, TOC4F9, upon reactivity with O2 at low temperature. A significantly expanded kinetic and mechanistic study of TOC4F9 formation...
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| Language: | en_US |
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2020
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| Online Access: | https://hdl.handle.net/2144/40354 |