Restricted rotation in sterically hindered diarylamines : structural requirements, synthesis, and applications of a new class of atropisomers
Although the stereochemistry of most atropisomers arises from slow rotation about a C-C bond, the ability of the nitrogen atom to adopt a planar geometry promotes conformational rigidity in anilides and aryl ureas. Diarylamines are closely related in architecture to the conformationally stable diary...
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University of Bristol
2019
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| Online Access: | https://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.767984 |
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