Geometry constrained main-group compounds for the activation of small molecules

A series of base-supported group 13 complexes bearing N,N-bis(3,5-di-tert-butyl-2-phenolate)amide pincer ligand, (ONO)<sup>3-</sup>, are reported (E(ONO)·L (E = B, Al, Ga; L = Lewis base). B(ONO) type compounds were formed in-situ and are capable of THF activation. Alternatively, a NMe&l...

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Bibliographic Details
Main Author: Lo, Siu Kwan
Other Authors: Goicoechea, Jose
Published: University of Oxford 2018
Online Access:https://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.757879