Boron and carbon Lewis acids in FLPs for the activation of σ and π bonds
In the presence of B(C6F5)3 five-membered heteroarenes undergo dehydrosilylation and hydrosilylation with silanes. The former, favoured on addition of a weak base, produces H2 as a by-product making the process catalytic in B(C6F5)3 but also enabling competitive heteroarene hydrogenation. The dehydr...
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University of Manchester
2016
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| Online Access: | https://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.748008 |