Assessing the scope of reductive cyclisations of lactones using SmI2-H2O
This report firstly describes the 5-exo-dig,6-exo-trig cascade cyclisation of 6-membered allenyl lactones for the formation of highly decorated 7,6-fused bicycles using the SmI2-H2O reducing system. Preliminary studies showed that 5-exo-dig,5-exo-trig cascade reactions successfully yield 7,5-fused b...
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University of Manchester
2017
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| Online Access: | https://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.728200 |