New approaches to the catalytic activation of arenes and carbonyls
The activation of styrene towards nucleophilic addition and a Diels‒Alder reaction through η6-binding to ruthenium in [RuCp(η6-stryene)]PF6 has been achieved. Nucleophilic addition solely took place at the terminal carbon of the alkene, to give the anti-Markovnikov product. Good to excellent convers...
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University of Bath
2016
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| Online Access: | https://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.687388 |