Lanthanide replacement in organic synthesis : calcium-mediated Luche-type reduction of α,β-functionalised ketones
Complexes of alkaline earth metals (Ca, Sr, and Ba) exhibit lanthanide-like reactivity and coordination behaviour, thus it is not surprising that such alkaline earth metals are also often compared to early f-block lanthanides. Attention has been focused on calcium-catalysed reactions as calcium, the...
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Imperial College London
2013
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Online Access: | http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.679638 |