Steric and kinetic effects of the t-butyl substituent at phosphorus

A study of both the steric and kinetic effects of the t-butyl substituent at phosphorus in phosphonium salts and thiophosphoiyl compounds has been made. In phosphonium salts one t-butyl substituent was found to have a relatively small effect on the rate of alkaline hydrolysis, whereas two t-butyl su...

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Bibliographic Details
Main Author: De'ath, Norman John
Published: University of Leicester 1970
Subjects:
540
Online Access:http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.673985