Rhodium-catalysed [(3+2)+2] carbocyclisation of heteroatom-substituted alkenes and synthetic studies towards (+)-repin

The stereoselective construction of fused 5,7-bicycles has attracted considerable attention due to the ubiquity of this motif in complex biologically active sesquiterpene lactones (dehydrocostus lactone, helenalin). Transition metal-catalysed carbocyclisation reactions represent a highly attractive...

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Bibliographic Details
Main Author: Baikstis, Tomass
Published: University of Liverpool 2014
Subjects:
540
Online Access:http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.666712

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