Photoelectrochemical processes at the interface between two immiscible electrolyte solutions

This thesis is devoted to the photoelectrochemical characterisation of the interface between two immiscible electrolyte solutions. A number of new phenomena are reported and analysed. These include photoinitiated ion transfer, photosensitised ion transfer, interfacial photoanation of the [Ru(bpy)<...

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Main Author:	Brown, Alan R.
Published:	University of Edinburgh 1992
Subjects:	541.37
Online Access:	http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.642105

id	ndltd-bl.uk-oai-ethos.bl.uk-642105
record_format	oai_dc
spelling	ndltd-bl.uk-oai-ethos.bl.uk-6421052016-04-25T15:16:18ZPhotoelectrochemical processes at the interface between two immiscible electrolyte solutionsBrown, Alan R.1992This thesis is devoted to the photoelectrochemical characterisation of the interface between two immiscible electrolyte solutions. A number of new phenomena are reported and analysed. These include photoinitiated ion transfer, photosensitised ion transfer, interfacial photoanation of the [Ru(bpy)<SUB>3</SUB>]<SUP>2</SUP>+ ion and photoinitiated electron transfer. This last phenomenon takes place between the luminescent state of the [Ru(bpy)<SUB>3</SUB>]<SUP>2</SUP>+ ion and 7,7,8,8-tetracyanoquinodimethane, across the water/1,2-dichloroethane interface. A novel technique is presented to examine the ion transfer reactions of electrogenerated species, and data resulting from this technique are brought to bear on heterogeneous electron transfer reactions.541.37University of Edinburghhttp://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.642105http://hdl.handle.net/1842/12836Electronic Thesis or Dissertation
collection	NDLTD
sources	NDLTD
topic	541.37
spellingShingle	541.37 Brown, Alan R. Photoelectrochemical processes at the interface between two immiscible electrolyte solutions
description	This thesis is devoted to the photoelectrochemical characterisation of the interface between two immiscible electrolyte solutions. A number of new phenomena are reported and analysed. These include photoinitiated ion transfer, photosensitised ion transfer, interfacial photoanation of the [Ru(bpy)<SUB>3</SUB>]<SUP>2</SUP>+ ion and photoinitiated electron transfer. This last phenomenon takes place between the luminescent state of the [Ru(bpy)<SUB>3</SUB>]<SUP>2</SUP>+ ion and 7,7,8,8-tetracyanoquinodimethane, across the water/1,2-dichloroethane interface. A novel technique is presented to examine the ion transfer reactions of electrogenerated species, and data resulting from this technique are brought to bear on heterogeneous electron transfer reactions.
author	Brown, Alan R.
author_facet	Brown, Alan R.
author_sort	Brown, Alan R.
title	Photoelectrochemical processes at the interface between two immiscible electrolyte solutions
title_short	Photoelectrochemical processes at the interface between two immiscible electrolyte solutions
title_full	Photoelectrochemical processes at the interface between two immiscible electrolyte solutions
title_fullStr	Photoelectrochemical processes at the interface between two immiscible electrolyte solutions
title_full_unstemmed	Photoelectrochemical processes at the interface between two immiscible electrolyte solutions
title_sort	photoelectrochemical processes at the interface between two immiscible electrolyte solutions
publisher	University of Edinburgh
publishDate	1992
url	http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.642105
work_keys_str_mv	AT brownalanr photoelectrochemicalprocessesattheinterfacebetweentwoimmiscibleelectrolytesolutions
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Photoelectrochemical processes at the interface between two immiscible electrolyte solutions

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