Phobane complexes : restricted M-P rotation and their applications in catalysis
A series of alkyl phobane ligands PhobPR (R = nBu, iBu, sBu, sPn, ipn, CH2SiMe), menthyl, CH2C4H70) have been prepared by electrophilic Or nucleophilic routes as pure s- or a -isomers. Reaction of these ligands with [PtCI(NCIBu)2] or [PdCh(NCPh)2] gave square planar trans-[MCh(PhobPR)2] (M = Pt, Pd)...
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University of Bristol
2013
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| Online Access: | http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.619450 |