Synthesis, structure and electrochemistry of organometallic compounds bearing C(_n)N ligands
In this thesis, the synthesis of the organic cyanoacetylenes NCC≡CC(_6)H(_5) and NCC≡CC(_6)H(_4)-4-NMc(_2) and the metal cyanoacetylides Ru(C≡CC≡N)(PPh(_3))(_2)Cp, Ru(C≡CC≡N)(dppe)Cp* and Fe(C≡CC≡N)(dppe)Cp is presented and their coordination chemistry is explored. The structure and electrochemical...
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Durham University
2005
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| Online Access: | http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.551515 |