The synthesis and coordination chemistry of bulky beta-triketimines and application of their nickel(II) derivatives as ethylene polymerisation catalysts
The reaction of imidoyl chlorides IMC1-9 with lithium β-diketiminates Li(BDKx) (x = iPr, iPr2, tBu, Me3, iPr2/OMe) yields β-triketimines L1-16 which represent a new class of facially-coordinating neutral tridentate nitrogen ligands. The synthetic route is highly modular, allowing for wide variation...
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University of Manchester
2011
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| Online Access: | http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.539993 |