Developing new organochromium-mediated methodologies for organic synthesis
This report describes the addition of allyl bromide to benzaldehyde using polymer-supported chromium(ll) reagents. Six polymer-supported ligands for chromium(ll) were targeted of which four were synthesized successfully. The first ligand N-(2-hydroxy-3-(propenyl)benzylidene)benzylamine was prepared...
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University of Reading
2007
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ndltd-bl.uk-oai-ethos.bl.uk-4937462015-03-20T05:19:03ZDeveloping new organochromium-mediated methodologies for organic synthesisProutière, Séverine2007This report describes the addition of allyl bromide to benzaldehyde using polymer-supported chromium(ll) reagents. Six polymer-supported ligands for chromium(ll) were targeted of which four were synthesized successfully. The first ligand N-(2-hydroxy-3-(propenyl)benzylidene)benzylamine was prepared and polymerized to give the first PS-ligand. Secondly salicylaldehyde was reacted with 4-amlnomethylstyrene to give N-(2-hydroxybenzylidene)-4-vinylbenzylamine. Further polymerization resulted the second polymeric imine ligand. (±)-trans-1,2-Bis-(2-hydroxy-3-tert-butyl-5-styryl)benzylldene diaminocyclohexane was prepared and two different polymers were synthesised.547.05532University of Readinghttp://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.493746Electronic Thesis or Dissertation |
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547.05532 |
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547.05532 Proutière, Séverine Developing new organochromium-mediated methodologies for organic synthesis |
| description |
This report describes the addition of allyl bromide to benzaldehyde using polymer-supported chromium(ll) reagents. Six polymer-supported ligands for chromium(ll) were targeted of which four were synthesized successfully. The first ligand N-(2-hydroxy-3-(propenyl)benzylidene)benzylamine was prepared and polymerized to give the first PS-ligand. Secondly salicylaldehyde was reacted with 4-amlnomethylstyrene to give N-(2-hydroxybenzylidene)-4-vinylbenzylamine. Further polymerization resulted the second polymeric imine ligand. (±)-trans-1,2-Bis-(2-hydroxy-3-tert-butyl-5-styryl)benzylldene diaminocyclohexane was prepared and two different polymers were synthesised. |
| author |
Proutière, Séverine |
| author_facet |
Proutière, Séverine |
| author_sort |
Proutière, Séverine |
| title |
Developing new organochromium-mediated methodologies for organic synthesis |
| title_short |
Developing new organochromium-mediated methodologies for organic synthesis |
| title_full |
Developing new organochromium-mediated methodologies for organic synthesis |
| title_fullStr |
Developing new organochromium-mediated methodologies for organic synthesis |
| title_full_unstemmed |
Developing new organochromium-mediated methodologies for organic synthesis |
| title_sort |
developing new organochromium-mediated methodologies for organic synthesis |
| publisher |
University of Reading |
| publishDate |
2007 |
| url |
http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.493746 |
| work_keys_str_mv |
AT proutiereseverine developingneworganochromiummediatedmethodologiesfororganicsynthesis |
| _version_ |
1716790270396203008 |