Synthesis of adamantanoid dienones : decarboxylation studies in 2,7-dioxabicyclo[2,2,1] systems

The synthesis of two adamantanoid dienones (3) and (4) has been achieved from the phenolic iodide (l) via an Ar,-6 participation involving desaromatisation. The phenolic iodide was synthesised as a mixture of stereoisomers and on heating in a sealed tube with potassium t-butoxide in t-butanol two di...

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Bibliographic Details
Main Author: Miller, James Edward
Published: University of Leicester 1977
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Online Access:http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.465683