Some aspects of the electrochemical behaviour of zinc

The active region of the dissolution of zinc in flowing electrolyte has been examined. In certain circumstances the active dissolution is extended indefinitely when silicate ion is present. Double-layer capacitance measurements have been made and the results confirm earlier observations that it is p...

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Bibliographic Details
Main Author:	Marshall, Alan
Published:	Loughborough University 1975
Subjects:	541.37
Online Access:	https://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.464995

id	ndltd-bl.uk-oai-ethos.bl.uk-464995
record_format	oai_dc
spelling	ndltd-bl.uk-oai-ethos.bl.uk-4649952019-01-29T03:22:52ZSome aspects of the electrochemical behaviour of zincMarshall, Alan1975The active region of the dissolution of zinc in flowing electrolyte has been examined. In certain circumstances the active dissolution is extended indefinitely when silicate ion is present. Double-layer capacitance measurements have been made and the results confirm earlier observations that it is possible to study the electrode/electrolyte solution interphase free from the intrusion of adsorbed anions. It is also shown that the silicate ion is adsorbed at the electrode at potentials close to the dissolution potential. The exchange reaction has been studied and improvements made to earlier reported data. A proposed mechanism consistent with the new kinetic data appears to be satisfactory.541.37Loughborough Universityhttps://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.464995https://dspace.lboro.ac.uk/2134/36081Electronic Thesis or Dissertation
collection	NDLTD
sources	NDLTD
topic	541.37
spellingShingle	541.37 Marshall, Alan Some aspects of the electrochemical behaviour of zinc
description	The active region of the dissolution of zinc in flowing electrolyte has been examined. In certain circumstances the active dissolution is extended indefinitely when silicate ion is present. Double-layer capacitance measurements have been made and the results confirm earlier observations that it is possible to study the electrode/electrolyte solution interphase free from the intrusion of adsorbed anions. It is also shown that the silicate ion is adsorbed at the electrode at potentials close to the dissolution potential. The exchange reaction has been studied and improvements made to earlier reported data. A proposed mechanism consistent with the new kinetic data appears to be satisfactory.
author	Marshall, Alan
author_facet	Marshall, Alan
author_sort	Marshall, Alan
title	Some aspects of the electrochemical behaviour of zinc
title_short	Some aspects of the electrochemical behaviour of zinc
title_full	Some aspects of the electrochemical behaviour of zinc
title_fullStr	Some aspects of the electrochemical behaviour of zinc
title_full_unstemmed	Some aspects of the electrochemical behaviour of zinc
title_sort	some aspects of the electrochemical behaviour of zinc
publisher	Loughborough University
publishDate	1975
url	https://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.464995
work_keys_str_mv	AT marshallalan someaspectsoftheelectrochemicalbehaviourofzinc
_version_	1718968919325147136

Some aspects of the electrochemical behaviour of zinc

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