A study of the co-ordination behaviour of the chalcogenocyanate ions

A study of the co-ordination behaviour of the chalcogenocyanate ions

The coordination behaviour of the pseudohalide ions (NCO ̄ NCS ̄ NCSe ̄ NCTe ̄) has been studied. A number of N- and S-bonded thiocyanate complexes of rhodium(I), of the type Rh(PPh3)2(L)CNS (L = ligand), have been prepared. The mode of linkage of the thiocyanate group has been established by means...

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Main Author: Anderson, S. J.
Published: Loughborough University 1974
Subjects:
541
Online Access:http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.447881
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spelling ndltd-bl.uk-oai-ethos.bl.uk-4478812018-08-07T03:17:10ZA study of the co-ordination behaviour of the chalcogenocyanate ionsAnderson, S. J.1974The coordination behaviour of the pseudohalide ions (NCO ̄ NCS ̄ NCSe ̄ NCTe ̄) has been studied. A number of N- and S-bonded thiocyanate complexes of rhodium(I), of the type Rh(PPh3)2(L)CNS (L = ligand), have been prepared. The mode of linkage of the thiocyanate group has been established by means of infrared spectral measurements. The preparation of Rh(PPh3)2(piperidine)NCS clearly demonstrates that a strongly π-accepting ligand such as CO is not a prerequisite for a N-thiocyanato complex of the type Rh(PPh3)2(L)NCS.541Loughborough Universityhttp://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.447881https://dspace.lboro.ac.uk/2134/33955Electronic Thesis or Dissertation
collection NDLTD
sources NDLTD
topic 541
spellingShingle 541
Anderson, S. J.
A study of the co-ordination behaviour of the chalcogenocyanate ions
description The coordination behaviour of the pseudohalide ions (NCO ̄ NCS ̄ NCSe ̄ NCTe ̄) has been studied. A number of N- and S-bonded thiocyanate complexes of rhodium(I), of the type Rh(PPh3)2(L)CNS (L = ligand), have been prepared. The mode of linkage of the thiocyanate group has been established by means of infrared spectral measurements. The preparation of Rh(PPh3)2(piperidine)NCS clearly demonstrates that a strongly π-accepting ligand such as CO is not a prerequisite for a N-thiocyanato complex of the type Rh(PPh3)2(L)NCS.
author Anderson, S. J.
author_facet Anderson, S. J.
author_sort Anderson, S. J.
title A study of the co-ordination behaviour of the chalcogenocyanate ions
title_short A study of the co-ordination behaviour of the chalcogenocyanate ions
title_full A study of the co-ordination behaviour of the chalcogenocyanate ions
title_fullStr A study of the co-ordination behaviour of the chalcogenocyanate ions
title_full_unstemmed A study of the co-ordination behaviour of the chalcogenocyanate ions
title_sort study of the co-ordination behaviour of the chalcogenocyanate ions
publisher Loughborough University
publishDate 1974
url http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.447881
work_keys_str_mv AT andersonsj astudyofthecoordinationbehaviourofthechalcogenocyanateions
AT andersonsj studyofthecoordinationbehaviourofthechalcogenocyanateions
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