A study of the co-ordination behaviour of the chalcogenocyanate ions
The coordination behaviour of the pseudohalide ions (NCO ̄ NCS ̄ NCSe ̄ NCTe ̄) has been studied. A number of N- and S-bonded thiocyanate complexes of rhodium(I), of the type Rh(PPh3)2(L)CNS (L = ligand), have been prepared. The mode of linkage of the thiocyanate group has been established by means...
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Loughborough University
1974
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| Online Access: | http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.447881 |
| Summary: | The coordination behaviour of the pseudohalide ions (NCO ̄ NCS ̄ NCSe ̄ NCTe ̄) has been studied. A number of N- and S-bonded thiocyanate complexes of rhodium(I), of the type Rh(PPh3)2(L)CNS (L = ligand), have been prepared. The mode of linkage of the thiocyanate group has been established by means of infrared spectral measurements. The preparation of Rh(PPh3)2(piperidine)NCS clearly demonstrates that a strongly π-accepting ligand such as CO is not a prerequisite for a N-thiocyanato complex of the type Rh(PPh3)2(L)NCS. |
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