Novel catalysts and mechanistic investigation in dioxirane-mediated oxidations
The work described in this thesis follows the development of a family of achiral trifluoroketones, which were studied for use as ketone catalysts for the in situ generation of dioxiranes. One of the ketones investigated was a novel solid phase polymer-bound ketone, which led to a new area for dioxir...
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Loughborough University
2000
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ndltd-bl.uk-oai-ethos.bl.uk-3436952018-08-07T03:17:09ZNovel catalysts and mechanistic investigation in dioxirane-mediated oxidationsGrocock, Estella Louise2000The work described in this thesis follows the development of a family of achiral trifluoroketones, which were studied for use as ketone catalysts for the in situ generation of dioxiranes. One of the ketones investigated was a novel solid phase polymer-bound ketone, which led to a new area for dioxirane generation that could be of particular use in industry. Oxidations were run under monophasic and biphasic solvent reaction systems, with emphasis on the former. Ranges of reactions, including epoxidation and alcohol oxidations were examined to test the efficiency of each ketone. It was found that epoxidation reactions gave the most efficient oxidations, although secondary benzylic alcohols also gave evidence of oxidation.541KetonesLoughborough Universityhttp://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.343695https://dspace.lboro.ac.uk/2134/33767Electronic Thesis or Dissertation |
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NDLTD |
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NDLTD |
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541 Ketones |
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541 Ketones Grocock, Estella Louise Novel catalysts and mechanistic investigation in dioxirane-mediated oxidations |
| description |
The work described in this thesis follows the development of a family of achiral trifluoroketones, which were studied for use as ketone catalysts for the in situ generation of dioxiranes. One of the ketones investigated was a novel solid phase polymer-bound ketone, which led to a new area for dioxirane generation that could be of particular use in industry. Oxidations were run under monophasic and biphasic solvent reaction systems, with emphasis on the former. Ranges of reactions, including epoxidation and alcohol oxidations were examined to test the efficiency of each ketone. It was found that epoxidation reactions gave the most efficient oxidations, although secondary benzylic alcohols also gave evidence of oxidation. |
| author |
Grocock, Estella Louise |
| author_facet |
Grocock, Estella Louise |
| author_sort |
Grocock, Estella Louise |
| title |
Novel catalysts and mechanistic investigation in dioxirane-mediated oxidations |
| title_short |
Novel catalysts and mechanistic investigation in dioxirane-mediated oxidations |
| title_full |
Novel catalysts and mechanistic investigation in dioxirane-mediated oxidations |
| title_fullStr |
Novel catalysts and mechanistic investigation in dioxirane-mediated oxidations |
| title_full_unstemmed |
Novel catalysts and mechanistic investigation in dioxirane-mediated oxidations |
| title_sort |
novel catalysts and mechanistic investigation in dioxirane-mediated oxidations |
| publisher |
Loughborough University |
| publishDate |
2000 |
| url |
http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.343695 |
| work_keys_str_mv |
AT grocockestellalouise novelcatalystsandmechanisticinvestigationindioxiranemediatedoxidations |
| _version_ |
1718718744086183936 |