Mechanistic and synthetic studies with alkylcobaloximes : a new method for preparing oxygen-labelled aldehydes and ketones
1. There is a lack of suitable methods for enriching aldehydes and ketones at the oxygen position. We have shown that imine (-C-N-) derivatives (iminium salts, N-l-haloalkylamides and enamides) are readily hydrolysed with 1 mol. equiv. of [170]/180]water to yield the parent [170)/(1801-labelled carb...
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University of Warwick
1982
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| Online Access: | https://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.330757 |