o-Nitrosophenol complexes and their synthetic potential
Interaction of triphenylphosphine with Ni(XqO)2 (XqOH = 2-nitrosophenol, X = 4-chloro, 4-bromo, 4-methyl and 5-methoxy) resulted in deoxygenation to give mainly bis(2-triphenylphosphiniminophenolato) nickel(ll), Similarly the interaction of triphenyl phosphine with Zn(qO)2 (qOH = 5-methoxy-2- nitros...
| Main Author: | |
|---|---|
| Published: |
London Metropolitan University
1980
|
| Subjects: | |
| Online Access: | https://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.259221 |
| id |
ndltd-bl.uk-oai-ethos.bl.uk-259221 |
|---|---|
| record_format |
oai_dc |
| spelling |
ndltd-bl.uk-oai-ethos.bl.uk-2592212018-11-08T03:19:48Zo-Nitrosophenol complexes and their synthetic potentialKensett, Malcolm James1980Interaction of triphenylphosphine with Ni(XqO)2 (XqOH = 2-nitrosophenol, X = 4-chloro, 4-bromo, 4-methyl and 5-methoxy) resulted in deoxygenation to give mainly bis(2-triphenylphosphiniminophenolato) nickel(ll), Similarly the interaction of triphenyl phosphine with Zn(qO)2 (qOH = 5-methoxy-2- nitrosophenol) involved deoxygenation and formation of bis(2-triphenylphosphiniminophenolato)zinc(ll). Action of dilute hydrochloric acid on these complexes afforded the hydrochlorides of the corresponding N(2-hydroxybenzene)iminotriphenyl phosphoranes. The hydrochlorides on neutralisation with sodium carbonate gave, in most cases, the parent N(2-hydroxybenzene)- iminotriphenyl phosphorene.540540 Chemistry & allied sciencesLondon Metropolitan Universityhttps://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.259221http://repository.londonmet.ac.uk/2998/Electronic Thesis or Dissertation |
| collection |
NDLTD |
| sources |
NDLTD |
| topic |
540 540 Chemistry & allied sciences |
| spellingShingle |
540 540 Chemistry & allied sciences Kensett, Malcolm James o-Nitrosophenol complexes and their synthetic potential |
| description |
Interaction of triphenylphosphine with Ni(XqO)2 (XqOH = 2-nitrosophenol, X = 4-chloro, 4-bromo, 4-methyl and 5-methoxy) resulted in deoxygenation to give mainly bis(2-triphenylphosphiniminophenolato) nickel(ll), Similarly the interaction of triphenyl phosphine with Zn(qO)2 (qOH = 5-methoxy-2- nitrosophenol) involved deoxygenation and formation of bis(2-triphenylphosphiniminophenolato)zinc(ll). Action of dilute hydrochloric acid on these complexes afforded the hydrochlorides of the corresponding N(2-hydroxybenzene)iminotriphenyl phosphoranes. The hydrochlorides on neutralisation with sodium carbonate gave, in most cases, the parent N(2-hydroxybenzene)- iminotriphenyl phosphorene. |
| author |
Kensett, Malcolm James |
| author_facet |
Kensett, Malcolm James |
| author_sort |
Kensett, Malcolm James |
| title |
o-Nitrosophenol complexes and their synthetic potential |
| title_short |
o-Nitrosophenol complexes and their synthetic potential |
| title_full |
o-Nitrosophenol complexes and their synthetic potential |
| title_fullStr |
o-Nitrosophenol complexes and their synthetic potential |
| title_full_unstemmed |
o-Nitrosophenol complexes and their synthetic potential |
| title_sort |
o-nitrosophenol complexes and their synthetic potential |
| publisher |
London Metropolitan University |
| publishDate |
1980 |
| url |
https://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.259221 |
| work_keys_str_mv |
AT kensettmalcolmjames onitrosophenolcomplexesandtheirsyntheticpotential |
| _version_ |
1718789355877695488 |