Structures and Rotational Constants of the Propiolic Acid Formic Acid Dimer, 1-Fluoronaphthalene, and 2-Fluoronaphthalene Determined Using Microwave Spectroscopy

Structures and Rotational Constants of the Propiolic Acid Formic Acid Dimer, 1-Fluoronaphthalene, and 2-Fluoronaphthalene Determined Using Microwave Spectroscopy

Fourier transform microwave spectroscopy was used to measure the microwave spectrum and rotational constants of the propiolic acid formic acid hydrogen bonded dimer, 1- fluoronaphthalene, and 2-fluoronaphthalene. Multiple isotopomers of propiolic acid formic acid dimer were studied. From this data,...

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Main Author: Carey, Spencer James
Other Authors: Kukolich, Stephen G.
Language:en
Published: The University of Arizona. 2013
Online Access:http://hdl.handle.net/10150/297518
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spelling ndltd-arizona.edu-oai-arizona.openrepository.com-10150-2975182015-10-23T05:19:36Z Structures and Rotational Constants of the Propiolic Acid Formic Acid Dimer, 1-Fluoronaphthalene, and 2-Fluoronaphthalene Determined Using Microwave Spectroscopy Carey, Spencer James Kukolich, Stephen G. Fourier transform microwave spectroscopy was used to measure the microwave spectrum and rotational constants of the propiolic acid formic acid hydrogen bonded dimer, 1- fluoronaphthalene, and 2-fluoronaphthalene. Multiple isotopomers of propiolic acid formic acid dimer were studied. From this data, the structural details of this system were determined. The basic theoretical concepts behind rotational spectroscopy, the microwave spectrometer used in the experiments, and calculation methods used are detailed. Present progress of work studying the molecules 2-fluorobenzoic acid, 3-fluorobenzoic acid, 4-fluorobenzoic acid, their respective homodimers and heterodimers, and the dimers formed with formic acid are also discussed. 2013 text Electronic Thesis http://hdl.handle.net/10150/297518 en Copyright © is held by the author. Digital access to this material is made possible by the University Libraries, University of Arizona. Further transmission, reproduction or presentation (such as public display or performance) of protected items is prohibited except with permission of the author. The University of Arizona.
collection NDLTD
language en
sources NDLTD
description Fourier transform microwave spectroscopy was used to measure the microwave spectrum and rotational constants of the propiolic acid formic acid hydrogen bonded dimer, 1- fluoronaphthalene, and 2-fluoronaphthalene. Multiple isotopomers of propiolic acid formic acid dimer were studied. From this data, the structural details of this system were determined. The basic theoretical concepts behind rotational spectroscopy, the microwave spectrometer used in the experiments, and calculation methods used are detailed. Present progress of work studying the molecules 2-fluorobenzoic acid, 3-fluorobenzoic acid, 4-fluorobenzoic acid, their respective homodimers and heterodimers, and the dimers formed with formic acid are also discussed.
author2 Kukolich, Stephen G.
author_facet Kukolich, Stephen G.
Carey, Spencer James
author Carey, Spencer James
spellingShingle Carey, Spencer James
Structures and Rotational Constants of the Propiolic Acid Formic Acid Dimer, 1-Fluoronaphthalene, and 2-Fluoronaphthalene Determined Using Microwave Spectroscopy
author_sort Carey, Spencer James
title Structures and Rotational Constants of the Propiolic Acid Formic Acid Dimer, 1-Fluoronaphthalene, and 2-Fluoronaphthalene Determined Using Microwave Spectroscopy
title_short Structures and Rotational Constants of the Propiolic Acid Formic Acid Dimer, 1-Fluoronaphthalene, and 2-Fluoronaphthalene Determined Using Microwave Spectroscopy
title_full Structures and Rotational Constants of the Propiolic Acid Formic Acid Dimer, 1-Fluoronaphthalene, and 2-Fluoronaphthalene Determined Using Microwave Spectroscopy
title_fullStr Structures and Rotational Constants of the Propiolic Acid Formic Acid Dimer, 1-Fluoronaphthalene, and 2-Fluoronaphthalene Determined Using Microwave Spectroscopy
title_full_unstemmed Structures and Rotational Constants of the Propiolic Acid Formic Acid Dimer, 1-Fluoronaphthalene, and 2-Fluoronaphthalene Determined Using Microwave Spectroscopy
title_sort structures and rotational constants of the propiolic acid formic acid dimer, 1-fluoronaphthalene, and 2-fluoronaphthalene determined using microwave spectroscopy
publisher The University of Arizona.
publishDate 2013
url http://hdl.handle.net/10150/297518
work_keys_str_mv AT careyspencerjames structuresandrotationalconstantsofthepropiolicacidformicaciddimer1fluoronaphthaleneand2fluoronaphthalenedeterminedusingmicrowavespectroscopy
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