THE VIBRATIONAL AND ELECTRONIC ABSORPTION SPECTRA OF SILVER-LITHIUM, SILVER-SODIUM, COPPER-LITHIUM, AND COPPER-SODIUM FROM SINGLE MOLECULES TO SMALL PARTICLES.

Vibrational and electronic absorption spectra of metal alloy molecules and small particles have been measured. The matrix isolation technique was used to produce the samples. Dissimilar metals were combined to provide far infrared vibrational activity. Through the study of the electronic and vibrati...

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Main Author:	PFLIBSEN, KENT PAUL.
Language:	en
Published:	The University of Arizona. 1984
Subjects:	Copper > Spectra. Electronic excitation. Silver > Spectra. Infrared spectroscopy.
Online Access:	http://hdl.handle.net/10150/187656

id	ndltd-arizona.edu-oai-arizona.openrepository.com-10150-187656
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spelling	ndltd-arizona.edu-oai-arizona.openrepository.com-10150-1876562016-02-14T03:00:37Z THE VIBRATIONAL AND ELECTRONIC ABSORPTION SPECTRA OF SILVER-LITHIUM, SILVER-SODIUM, COPPER-LITHIUM, AND COPPER-SODIUM FROM SINGLE MOLECULES TO SMALL PARTICLES. PFLIBSEN, KENT PAUL. Copper -- Spectra. Electronic excitation. Silver -- Spectra. Infrared spectroscopy. Vibrational and electronic absorption spectra of metal alloy molecules and small particles have been measured. The matrix isolation technique was used to produce the samples. Dissimilar metals were combined to provide far infrared vibrational activity. Through the study of the electronic and vibrational excitation spectra, metallic interatomic binding potential characteristics could be investigated. The absorption spectra of the molecular systems were modelled using the extended Hueckel method, for the electronic excitations, and a dynamical matrix-normal mode technique for the vibrational excitations. Surface plasmon absorption, from the metal alloy particles, could not be measured but surface phonon absorption was measured. Electronic and vibrational absorption lines in alloyed metal molecules were measured and compared to the calculations. A surface diffusion model was developed to explain the dependences of molecule and particle size on the experimentally controlled system parameters. 1984 text Dissertation-Reproduction (electronic) http://hdl.handle.net/10150/187656 690928129 8412673 en Copyright © is held by the author. Digital access to this material is made possible by the University Libraries, University of Arizona. Further transmission, reproduction or presentation (such as public display or performance) of protected items is prohibited except with permission of the author. The University of Arizona.
collection	NDLTD
language	en
sources	NDLTD
topic	Copper -- Spectra. Electronic excitation. Silver -- Spectra. Infrared spectroscopy.
spellingShingle	Copper -- Spectra. Electronic excitation. Silver -- Spectra. Infrared spectroscopy. PFLIBSEN, KENT PAUL. THE VIBRATIONAL AND ELECTRONIC ABSORPTION SPECTRA OF SILVER-LITHIUM, SILVER-SODIUM, COPPER-LITHIUM, AND COPPER-SODIUM FROM SINGLE MOLECULES TO SMALL PARTICLES.
description	Vibrational and electronic absorption spectra of metal alloy molecules and small particles have been measured. The matrix isolation technique was used to produce the samples. Dissimilar metals were combined to provide far infrared vibrational activity. Through the study of the electronic and vibrational excitation spectra, metallic interatomic binding potential characteristics could be investigated. The absorption spectra of the molecular systems were modelled using the extended Hueckel method, for the electronic excitations, and a dynamical matrix-normal mode technique for the vibrational excitations. Surface plasmon absorption, from the metal alloy particles, could not be measured but surface phonon absorption was measured. Electronic and vibrational absorption lines in alloyed metal molecules were measured and compared to the calculations. A surface diffusion model was developed to explain the dependences of molecule and particle size on the experimentally controlled system parameters.
author	PFLIBSEN, KENT PAUL.
author_facet	PFLIBSEN, KENT PAUL.
author_sort	PFLIBSEN, KENT PAUL.
title	THE VIBRATIONAL AND ELECTRONIC ABSORPTION SPECTRA OF SILVER-LITHIUM, SILVER-SODIUM, COPPER-LITHIUM, AND COPPER-SODIUM FROM SINGLE MOLECULES TO SMALL PARTICLES.
title_short	THE VIBRATIONAL AND ELECTRONIC ABSORPTION SPECTRA OF SILVER-LITHIUM, SILVER-SODIUM, COPPER-LITHIUM, AND COPPER-SODIUM FROM SINGLE MOLECULES TO SMALL PARTICLES.
title_full	THE VIBRATIONAL AND ELECTRONIC ABSORPTION SPECTRA OF SILVER-LITHIUM, SILVER-SODIUM, COPPER-LITHIUM, AND COPPER-SODIUM FROM SINGLE MOLECULES TO SMALL PARTICLES.
title_fullStr	THE VIBRATIONAL AND ELECTRONIC ABSORPTION SPECTRA OF SILVER-LITHIUM, SILVER-SODIUM, COPPER-LITHIUM, AND COPPER-SODIUM FROM SINGLE MOLECULES TO SMALL PARTICLES.
title_full_unstemmed	THE VIBRATIONAL AND ELECTRONIC ABSORPTION SPECTRA OF SILVER-LITHIUM, SILVER-SODIUM, COPPER-LITHIUM, AND COPPER-SODIUM FROM SINGLE MOLECULES TO SMALL PARTICLES.
title_sort	vibrational and electronic absorption spectra of silver-lithium, silver-sodium, copper-lithium, and copper-sodium from single molecules to small particles.
publisher	The University of Arizona.
publishDate	1984
url	http://hdl.handle.net/10150/187656
work_keys_str_mv	AT pflibsenkentpaul thevibrationalandelectronicabsorptionspectraofsilverlithiumsilversodiumcopperlithiumandcoppersodiumfromsinglemoleculestosmallparticles AT pflibsenkentpaul vibrationalandelectronicabsorptionspectraofsilverlithiumsilversodiumcopperlithiumandcoppersodiumfromsinglemoleculestosmallparticles
_version_	1718188280888950784

THE VIBRATIONAL AND ELECTRONIC ABSORPTION SPECTRA OF SILVER-LITHIUM, SILVER-SODIUM, COPPER-LITHIUM, AND COPPER-SODIUM FROM SINGLE MOLECULES TO SMALL PARTICLES.

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