Ring opening of tetraaryl thiirane cation radicals.
Ring opening of tetraaryl thiirane cation radical was studied. The cation radical of tetraaryl thiirane generated photochemically undergoes C-C bond cleavage driven by inherent ring strain. This ring cleavage occurs in a stereospecific conrotatory manner at low temperature. However, this stereospeci...
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| Language: | en |
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The University of Arizona.
1994
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| Online Access: | http://hdl.handle.net/10150/186684 |