Stabilization of electron-deficient sulfur by neighboring sulfur and oxygen groups.
The mesocyclic trithioether 1,4,7-trithiacyclononane shows neighboring group participation upon oxidation as evidenced by the peak potential for oxidation in cyclic voltammetry, 0.9 V versus Ag/0.1 M AgNO₃, and by the formation of its monosulfoxide by controlled potential electrolysis in an overall...
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| Language: | en |
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The University of Arizona.
1989
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| Online Access: | http://hdl.handle.net/10150/184977 |