Synthesis and Characterization of Iron-Amide and Iron-Imide-Sulfide Clusters

The iron-molybdenum cofactor (FeMo cofactor) is the catalytic center of nitrogen fixation in molybdenum-dependent nitrognease enzymes. The resting state cofactor is a complex [MoFe7S9X] cluster, in which the central ligand X is a central hexacoordinated monoatomic light atom (2p), and the exact iden...

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Bibliographic Details
Main Author: Zhang, Wei
Language:en
Published: 2011
Subjects:
Online Access:http://hdl.handle.net/10012/6189

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