Rapid Synthesis, Characterization, and Catalytic Function of Rhodium(III) and Iridium(III) Chloro-bridged Dimers

Rapid Synthesis, Characterization, and Catalytic Function of Rhodium(III) and Iridium(III) Chloro-bridged Dimers

Rh(III) and Ir(III) dimeric complexes with tunable cyclopentadienyl (Cp) rings have proven versatile for both catalysis and as synthetic precursors. An efficient microwave method to synthesize Rh(III) and Ir(III) dimeric complexes [(η5-ring)MCl]2(μ2-Cl)2, (where (η5-ring)MCl = (η5-Me4C5R)Rh(III)Cl o...

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Bibliographic Details
Main Author: Brown, Loren
Other Authors: Chemistry
Format: Others
Published: Virginia Tech 2019
Subjects:
iridium
rhodium
lactone
oxidative lactonization
transfer dehydrogenation
microwave synthesis
ligand effects
Online Access:http://hdl.handle.net/10919/89732

Internet

http://hdl.handle.net/10919/89732

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